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D electron count

Index D electron count

The d electron count is a chemistry formalism used to describe the electron configuration of the valence electrons of a transition metal center in a coordination complex. [1]

45 relations: Aufbau principle, Chemistry, Chromium hexacarbonyl, Cisplatin, Cobaltocene, Coordination complex, Crystal field theory, Dichlorobis(ethylenediamine)nickel(II), Electromagnetic spectrum, Electron configuration, Ferrocene, Ferroin, Hexamminecobalt(III) chloride, Hydrogen-like atom, Iron pentacarbonyl, Ligand field theory, Molecular orbital theory, Molybdenum hexacarbonyl, Molybdenum(V) chloride, Nickel tetracarbonyl, Nickelocene, Octahedral molecular geometry, Potassium ferrioxalate, Reinecke's salt, Schwartz's reagent, Schweizer's reagent, Sodium cobaltinitrite, Spin states (d electrons), Tanabe–Sugano diagram, Tetrahedral molecular geometry, Tetrakis(triphenylphosphine)palladium(0), Titanium tetrachloride, Titanocene dicarbonyl, Titanocene dichloride, Transition metal, Trigonal bipyramidal molecular geometry, Valence electron, Vanadium hexacarbonyl, Vanadium tetrachloride, Vanadocene dichloride, Vanadyl acetylacetonate, Vaska's complex, Wilkinson's catalyst, Zeise's salt, 18-electron rule.

Aufbau principle

The aufbau principle states that in the ground state of an atom or ion, electrons fill atomic orbitals of the lowest available energy levels before occupying higher levels.

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Chemistry

Chemistry is the scientific discipline involved with compounds composed of atoms, i.e. elements, and molecules, i.e. combinations of atoms: their composition, structure, properties, behavior and the changes they undergo during a reaction with other compounds.

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Chromium hexacarbonyl

Chromium carbonyl, also known as chromium hexacarbonyl, is the chemical compound with the formula Cr(CO)6.

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Cisplatin

Cisplatin is a chemotherapy medication used to treat a number of cancers.

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Cobaltocene

Cobaltocene, known also as bis(cyclopentadienyl)cobalt(II) or even "bis Cp cobalt", is an organocobalt compound with the formula Co(C5H5)2.

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Coordination complex

In chemistry, a coordination complex consists of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands or complexing agents.

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Crystal field theory

Crystal Field Theory (CFT) is a model that describes the breaking of degeneracies of electron orbital states, usually d or f orbitals, due to a static electric field produced by a surrounding charge distribution (anion neighbors).

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Dichlorobis(ethylenediamine)nickel(II)

Dichlorobis(ethylenediamine)nickel(II) is the coordination compound with the formula NiCl2(en)2, where en.

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Electromagnetic spectrum

The electromagnetic spectrum is the range of frequencies (the spectrum) of electromagnetic radiation and their respective wavelengths and photon energies.

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Electron configuration

In atomic physics and quantum chemistry, the electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals.

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Ferrocene

Ferrocene is an organometallic compound with the formula Fe(C5H5)2.

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Ferroin

Ferroin is the chemical compound with the formula SO4, where o-phen is an abbreviation for 1,10-phenanthroline, a bidentate ligand.

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Hexamminecobalt(III) chloride

Hexaamminecobalt(III) chloride is the chemical compound with the formula Cl3.

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Hydrogen-like atom

A hydrogen-like ion is any atomic nucleus which has one electron and thus is isoelectronic with hydrogen.

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Iron pentacarbonyl

Iron pentacarbonyl, also known as iron carbonyl, is the compound with formula5.

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Ligand field theory

Ligand field theory (LFT) describes the bonding, orbital arrangement, and other characteristics of coordination complexes.

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Molecular orbital theory

In chemistry, molecular orbital (MO) theory is a method for determining molecular structure in which electrons are not assigned to individual bonds between atoms, but are treated as moving under the influence of the nuclei in the whole molecule.

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Molybdenum hexacarbonyl

Molybdenum hexacarbonyl (also called molybdenum carbonyl) is the chemical compound with the formula Mo(CO)6.

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Molybdenum(V) chloride

Molybdenum(V) chloride is the inorganic compound with the formula 2.

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Nickel tetracarbonyl

Nickel carbonyl (IUPAC name: tetracarbonylnickel) is the organonickel compound with the formula Ni(CO)4.

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Nickelocene

Nickelocene is the organonickel compound with the formula Ni(''η''5-C5H5)2.

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Octahedral molecular geometry

In chemistry, octahedral molecular geometry describes the shape of compounds with six atoms or groups of atoms or ligands symmetrically arranged around a central atom, defining the vertices of an octahedron.

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Potassium ferrioxalate

Potassium ferrioxalate, also known as potassium trisoxalatoferrate(III), is a chemical compound with the formula, where iron is in the +3 oxidation state.

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Reinecke's salt

Reinecke's salt is a chemical compound with the formula NH4·H2O.

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Schwartz's reagent

Schwartz's reagent is the common name for the chemical compound with the formula (C5H5)2ZrHCl, sometimes called zirconocene hydrochloride or zirconocene chloride hydride, and is named after Jeffrey Schwartz, a chemistry professor at Princeton University.

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Schweizer's reagent

Schweizer's reagent is the chemical complex tetraamminediaquacopper dihydroxide, (OH)2.

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Sodium cobaltinitrite

Sodium cobaltinitrite is a coordination compound with the formula Na3Co(NO2)6.

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Spin states (d electrons)

Spin states when describing transition metal coordination complexes refers to the potential spin configurations of the metal center's d electrons.

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Tanabe–Sugano diagram

Tanabe–Sugano diagrams are used in coordination chemistry to predict absorptions in the UV, visible and IR electromagnetic spectrum of coordination compounds.

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Tetrahedral molecular geometry

In a tetrahedral molecular geometry, a central atom is located at the center with four substituents that are located at the corners of a tetrahedron.

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Tetrakis(triphenylphosphine)palladium(0)

Tetrakis(triphenylphosphine)palladium(0) (sometimes called quatrotriphenylphosphine) is the chemical compound Pd4, often abbreviated Pd(PPh3)4, or rarely PdP4.

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Titanium tetrachloride

Titanium tetrachloride is the inorganic compound with the formula TiCl4.

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Titanocene dicarbonyl

Dicarbonylbis(cyclopentadienyl)titanium is the chemical compound with the formula (η5-C5H5)2Ti(CO)2, abbreviated Cp2Ti(CO)2.

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Titanocene dichloride

Titanocene dichloride is the organotitanium compound with the formula (''η''5-C5H5)2TiCl2, commonly abbreviated as Cp2TiCl2.

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Transition metal

In chemistry, the term transition metal (or transition element) has three possible meanings.

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Trigonal bipyramidal molecular geometry

In chemistry a trigonal bipyramid formation is a molecular geometry with one atom at the center and 5 more atoms at the corners of a triangular dipyramid.

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Valence electron

In chemistry, a valence electron is an outer shell electron that is associated with an atom, and that can participate in the formation of a chemical bond if the outer shell is not closed; in a single covalent bond, both atoms in the bond contribute one valence electron in order to form a shared pair.

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Vanadium hexacarbonyl

Vanadium hexacarbonyl is the inorganic compound with the formula V(CO)6.

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Vanadium tetrachloride

Vanadium tetrachloride is the inorganic compound with the formula VCl4.

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Vanadocene dichloride

Vanadocene dichloride is an organometallic complex with formula (''η''5-C5H5)2VCl2 (commonly abbreviated as Cp2VCl2).

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Vanadyl acetylacetonate

Vanadyl acetylacetonate is the chemical compound with the formula VO(acac)2, where acac– is the conjugate base of acetylacetone.

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Vaska's complex

Vaska's complex is the trivial name for the chemical compound trans-carbonylchlorobis(triphenylphosphine)iridium(I), which has the formula IrCl(CO)2.

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Wilkinson's catalyst

Wilkinson's catalyst, is the common name for chloridotris(triphenylphosphane)rhodium(I), a coordination complex of rhodium with the formula RhCl(PPh3)3 (Ph.

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Zeise's salt

Zeise's salt, potassium trichloro(ethene)platinate(II), is the chemical compound with the formula K·H2O.

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18-electron rule

The 18-electron rule is a rule used primarily for predicting and rationalizing formulae for stable metal complexes, especially organometallic compounds.

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References

[1] https://en.wikipedia.org/wiki/D_electron_count

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