30 relations: Aldehyde, Alkane, Aryl radical, Autoxidation, Azo compound, Barton reaction, Barton–McCombie deoxygenation, Benzene, Carboxylic acid, Chromic acid, Coupling reaction, Diethyl ether peroxide, Dissociation (chemistry), Dowd–Beckwith ring-expansion reaction, Fenton's reagent, Free-radical halogenation, Halogen, Homolysis (chemistry), Hunsdiecker reaction, Hydroxy group, Minisci reaction, Organic chemistry, Organic peroxide, Radical (chemistry), Radical initiator, Radical-nucleophilic aromatic substitution, Reactive intermediate, Substitution reaction, Ultraviolet, Wohl–Ziegler bromination.
Aldehyde
An aldehyde or alkanal is an organic compound containing a functional group with the structure −CHO, consisting of a carbonyl center (a carbon double-bonded to oxygen) with the carbon atom also bonded to hydrogen and to an R group, which is any generic alkyl or side chain.
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Alkane
In organic chemistry, an alkane, or paraffin (a historical name that also has other meanings), is an acyclic saturated hydrocarbon.
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Aryl radical
An aryl radical in organic chemistry is a reactive intermediate and an arene compound incorporating one free radical carbon atom as part of the ring structure.
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Autoxidation
Autoxidation is any oxidation that occurs in open air or in presence of oxygen (and sometimes UV radiation) and forms peroxides and hydroperoxides.
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Azo compound
Azo compounds are compounds bearing the functional group R−N.
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Barton reaction
The Barton reaction, also known as the Barton nitrite ester reaction, is a photochemical reaction that involves the photolysis of an alkyl nitrite to form a δ-nitroso alcohol.
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Barton–McCombie deoxygenation
The Barton–McCombie deoxygenation is an organic reaction in which an hydroxy functional group in an organic compound is replaced by a hydrogen to give an alkyl group.
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Benzene
Benzene is an important organic chemical compound with the chemical formula C6H6.
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Carboxylic acid
A carboxylic acid is an organic compound that contains a carboxyl group (C(.
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Chromic acid
The term chromic acid is usually used for a mixture made by adding concentrated sulfuric acid to a dichromate, which may contain a variety of compounds, including solid chromium trioxide.
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Coupling reaction
A coupling reaction in organic chemistry is a general term for a variety of reactions where two hydrocarbon fragments are coupled with the aid of a metal catalyst.
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Diethyl ether peroxide
Diethyl ether peroxides are a class of organic peroxides that slowly form in diethyl ether upon storage under air, light, or in the presence of metal by autoxidation.
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Dissociation (chemistry)
Dissociation in chemistry and biochemistry is a general process in which molecules (or ionic compounds such as salts, or complexes) separate or split into smaller particles such as atoms, ions or radicals, usually in a reversible manner.
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Dowd–Beckwith ring-expansion reaction
The Dowd–Beckwith ring-expansion reaction is an organic reaction in which a cyclic β-keto ester is expanded by up to 4 carbons in a free radical ring expansion reaction through an α-alkylhalo substituent.
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Fenton's reagent
Fenton's reagent is a solution of hydrogen peroxide with ferrous iron as a catalyst that is used to oxidize contaminants or waste waters.
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Free-radical halogenation
In organic chemistry, free-radical halogenation is a type of halogenation.
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Halogen
The halogens are a group in the periodic table consisting of five chemically related elements: fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and astatine (At).
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Homolysis (chemistry)
In chemistry, homolysis (from Greek ὅμοιος, homoios, "equal," and λύσις, lusis, "loosening") or homolytic fission is chemical bond dissociation of a molecule by a process where each of the fragments retains one of the originally bonded electrons.
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Hunsdiecker reaction
The Hunsdiecker reaction (also called the Borodin reaction or the Hunsdiecker–Borodin reaction) is a name reaction in organic chemistry whereby silver salts of carboxylic acids react with a halogen to produce an organic halide.
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Hydroxy group
A hydroxy or hydroxyl group is the entity with the formula OH.
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Minisci reaction
The Minisci reaction is a named reaction in organic chemistry.
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Organic chemistry
Organic chemistry is a chemistry subdiscipline involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms.
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Organic peroxide
Organic peroxides are organic compounds containing the peroxide functional group (ROOR′).
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Radical (chemistry)
In chemistry, a radical (more precisely, a free radical) is an atom, molecule, or ion that has an unpaired valence electron.
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Radical initiator
In chemistry, radical initiators are substances that can produce radical species under mild conditions and promote radical reactions.
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Radical-nucleophilic aromatic substitution
Radical-nucleophilic aromatic substitution or SRN1 in organic chemistry is a type of substitution reaction in which a certain substituent on an aromatic compound is replaced by a nucleophile through an intermediary free radical species: The substituent X is a halide and nucleophiles can be sodium amide, an alkoxide or a carbon nucleophile such as an enolate.
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Reactive intermediate
In chemistry, a reactive intermediate or an intermediate is a short-lived, high-energy, highly reactive molecule.
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Substitution reaction
Substitution reaction (also known as single displacement reaction or single substitution reaction) is a chemical reaction during which one functional group in a chemical compound is replaced by another functional group.
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Ultraviolet
Ultraviolet (UV) is electromagnetic radiation with a wavelength from 10 nm to 400 nm, shorter than that of visible light but longer than X-rays.
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Wohl–Ziegler bromination
The Wohl–Ziegler reaction is a chemical reaction that involves the allylic or benzylic bromination of hydrocarbons using an N-bromoimide and a radical initiator.
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Redirects here:
Free radical substitution, Free-radical substitution, Free-radical substitution reaction.
References
[1] https://en.wikipedia.org/wiki/Radical_substitution