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Wilkinson's catalyst

Index Wilkinson's catalyst

Wilkinson's catalyst, is the common name for chloridotris(triphenylphosphane)rhodium(I), a coordination complex of rhodium with the formula RhCl(PPh3)3 (Ph. [1]

37 relations: Aldehyde, Alkane, Alkene, Benzene, Bis(triphenylphosphine)rhodium carbonyl chloride, Carbon monoxide, Catecholborane, Coordination complex, Dimer (chemistry), Fluxional molecule, Geoffrey Wilkinson, Homogeneous catalysis, Hydridotetrakis(triphenylphosphine)rhodium(I), Hydroacylation, Hydroboration, Hydrogenation, Hydrosilylation, Inorganic Syntheses, Journal of the American Chemical Society, Journal of the Chemical Society, Migratory insertion, Organic Reactions, Oxidative addition, Phenyl group, Reductive elimination, Rhodium, Rhodium(III) chloride, Saturation (chemistry), Spin isomers of hydrogen, Tetrahedron Letters, Tetrahydrofuran, Tetrakis(triphenylphosphine)palladium(0), Toluene, Transition metal, Triphenylphosphine, Vaska's complex, 18-electron rule.

Aldehyde

An aldehyde or alkanal is an organic compound containing a functional group with the structure −CHO, consisting of a carbonyl center (a carbon double-bonded to oxygen) with the carbon atom also bonded to hydrogen and to an R group, which is any generic alkyl or side chain.

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Alkane

In organic chemistry, an alkane, or paraffin (a historical name that also has other meanings), is an acyclic saturated hydrocarbon.

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Alkene

In organic chemistry, an alkene is an unsaturated hydrocarbon that contains at least one carbon–carbon double bond.

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Benzene

Benzene is an important organic chemical compound with the chemical formula C6H6.

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Bis(triphenylphosphine)rhodium carbonyl chloride

Bis(triphenylphosphine)rhodium carbonyl chloride is the organorhodium complex with the formula RhCl(CO)2.

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Carbon monoxide

Carbon monoxide (CO) is a colorless, odorless, and tasteless gas that is slightly less dense than air.

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Catecholborane

Catecholborane (abbreviated HBcat) is an organoboron compound that is useful in organic synthesis.

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Coordination complex

In chemistry, a coordination complex consists of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands or complexing agents.

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Dimer (chemistry)

A dimer (di-, "two" + -mer, "parts") is an oligomer consisting of two monomers joined by bonds that can be either strong or weak, covalent or intermolecular.

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Fluxional molecule

Fluxional molecules are molecules that undergo dynamics such that some or all of their atoms interchange between symmetry-equivalent positions.

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Geoffrey Wilkinson

Sir Geoffrey Wilkinson FRS (14 July 1921 – 26 September 1996) was a Nobel laureate English chemist who pioneered inorganic chemistry and homogeneous transition metal catalysis.

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Homogeneous catalysis

In chemistry, homogeneous catalysis is catalysis in a solution by a soluble catalyst.

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Hydridotetrakis(triphenylphosphine)rhodium(I)

Hydridotetrakis(triphenylphosphine)rhodium(I) is the coordination complex with the formula HRh4.

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Hydroacylation

Hydroacylation is a type of organic reaction in which an alkene is inserted into the a formyl C-H bond.

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Hydroboration

In chemistry, hydroboration refers to the addition of a hydrogen-boron bond to C-C, C-N, and C-O double bonds, as well as C-C triple bonds.

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Hydrogenation

Hydrogenation – to treat with hydrogen – is a chemical reaction between molecular hydrogen (H2) and another compound or element, usually in the presence of a catalyst such as nickel, palladium or platinum.

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Hydrosilylation

Hydrosilylation, also called catalytic hydrosilation, describes the addition of Si-H bonds across unsaturated bonds.

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Inorganic Syntheses

Inorganic Syntheses is a book series which aims to publish "detailed and foolproof" procedures for the synthesis of inorganic compounds.

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Journal of the American Chemical Society

The Journal of the American Chemical Society (also known as JACS) is a weekly peer-reviewed scientific journal that was established in 1879 by the American Chemical Society.

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Journal of the Chemical Society

The Journal of the Chemical Society was a scientific journal established by the Chemical Society in 1849 as the Quarterly Journal of the Chemical Society.

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Migratory insertion

A migratory insertion is a type of reaction in organometallic chemistry wherein two ligands on a metal complex combine.

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Organic Reactions

Organic Reactions is a secondary reference which synthesizes the organic chemistry literature around particular chemical transformations.

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Oxidative addition

Oxidative addition and reductive elimination are two important and related classes of reactions in organometallic chemistry.

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Phenyl group

In organic chemistry, the phenyl group or phenyl ring is a cyclic group of atoms with the formula C6H5.

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Reductive elimination

Reductive elimination is an elementary step in organometallic chemistry in which the oxidation state of the metal center decreases while forming a new covalent bond between two ligands.

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Rhodium

Rhodium is a chemical element with symbol Rh and atomic number 45.

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Rhodium(III) chloride

Rhodium(III) chloride refers to inorganic compounds with the formula RhCl3(H2O)n, where n varies from 0 to 3.

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Saturation (chemistry)

In chemistry, saturation (from the Latin word saturare, meaning 'to fill') has diverse meanings, all based on the idea of reaching a maximum capacity.

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Spin isomers of hydrogen

Molecular hydrogen occurs in two isomeric forms, one with its two proton nuclear spins aligned parallel (orthohydrogen), the other with its two proton spins aligned antiparallel (parahydrogen).

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Tetrahedron Letters

Tetrahedron Letters is a weekly international journal for rapid publication of full original research papers in the field of organic chemistry.

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Tetrahydrofuran

Tetrahydrofuran (THF) is an organic compound with the formula (CH2)4O.

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Tetrakis(triphenylphosphine)palladium(0)

Tetrakis(triphenylphosphine)palladium(0) (sometimes called quatrotriphenylphosphine) is the chemical compound Pd4, often abbreviated Pd(PPh3)4, or rarely PdP4.

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Toluene

Toluene, also known as toluol, is an aromatic hydrocarbon.

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Transition metal

In chemistry, the term transition metal (or transition element) has three possible meanings.

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Triphenylphosphine

Triphenylphosphine (IUPAC name: triphenylphosphane) is a common organophosphorus compound with the formula P(C6H5)3 - often abbreviated to PPh3 or Ph3P.

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Vaska's complex

Vaska's complex is the trivial name for the chemical compound trans-carbonylchlorobis(triphenylphosphine)iridium(I), which has the formula IrCl(CO)2.

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18-electron rule

The 18-electron rule is a rule used primarily for predicting and rationalizing formulae for stable metal complexes, especially organometallic compounds.

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Redirects here:

Chlorotris(triphenylphosphine)rhodium, RhCl(PPh3)3, RhClP3, RhP3Cl, Rhodium(I) tris-(triphenylphosphine) chloride, Tris(triphenylphosphine)-rhodium chloride, Tris(triphenylphosphine)rhodium chloride, Wikinson's complex, Wilkinson Catalyst, Wilkinson catalyst, Wilkinson's Complex, Wilkinson's compound.

References

[1] https://en.wikipedia.org/wiki/Wilkinson's_catalyst

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