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Stereoisomerism

Index Stereoisomerism

In stereochemistry, stereoisomers are isomeric molecules that have the same molecular formula and sequence of bonded atoms (constitution), but differ in the three-dimensional orientations of their atoms in space. [1]

23 relations: Absolute configuration, Amino acid, Anomer, Asymmetric carbon, Atomic number, Atropisomer, Chemical formula, Chirality (chemistry), Covalent bond, Cyclohexane conformation, E-Z notation, Glycine, Isomer, Le Bel–Van 't Hoff rule, Meso compound, Mirror image, Optical rotation, Polarization (waves), Stereocenter, Stereochemistry, Structural isomer, Transition state, Van der Waals strain.

Absolute configuration

An absolute configuration refers to the spatial arrangement of the atoms of a chiral molecular entity (or group) and its stereochemical description e.g. R or S, referring to Rectus, or Sinister, respectively.

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Amino acid

Amino acids are organic compounds containing amine (-NH2) and carboxyl (-COOH) functional groups, along with a side chain (R group) specific to each amino acid.

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Anomer

An anomer is a type of geometric variation found in at certain atoms in carbohydrate molecules.

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Asymmetric carbon

An asymmetric carbon atom (chiral carbon) is a carbon atom that is attached to four different types of atoms or groups of atoms.

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Atomic number

The atomic number or proton number (symbol Z) of a chemical element is the number of protons found in the nucleus of an atom.

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Atropisomer

Atropisomers are stereoisomers arising because of hindered rotation about a single bond, where energy differences due to steric strain or other contributors create a barrier to rotation that is high enough to allow for isolation of individual conformers.

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Chemical formula

A chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, commas and plus (+) and minus (−) signs.

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Chirality (chemistry)

Chirality is a geometric property of some molecules and ions.

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Covalent bond

A covalent bond, also called a molecular bond, is a chemical bond that involves the sharing of electron pairs between atoms.

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Cyclohexane conformation

A cyclohexane conformation is any of several three-dimensional shapes that a cyclohexane molecule can assume while maintaining the integrity of its chemical bonds.

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E-Z notation

E-Z configuration, or the E-Z convention, is the IUPAC preferred method of describing the absolute stereochemistry of double bonds in organic chemistry.

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Glycine

Glycine (symbol Gly or G) is the amino acid that has a single hydrogen atom as its side chain.

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Isomer

An isomer (from Greek ἰσομερής, isomerès; isos.

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Le Bel–Van 't Hoff rule

In organic chemistry, the Le Bel–Van 't Hoff rule states that the number of stereoisomers of an organic compound containing no internal planes of symmetry is 2n, where n represents the number of asymmetric carbon atoms.

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Meso compound

A meso compound or meso isomer is a stereoisomer with an identical or superimposable mirror image i.e., a non-optically active member of a set of stereoisomers, at least two of which are optically active.

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Mirror image

A mirror image (in a plane mirror) is a reflected duplication of an object that appears almost identical, but is reversed in the direction perpendicular to the mirror surface.

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Optical rotation

Optical rotation or optical activity (sometimes referred to as rotary polarization) is the rotation of the plane of polarization of linearly polarized light as it travels through certain materials.

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Polarization (waves)

Polarization (also polarisation) is a property applying to transverse waves that specifies the geometrical orientation of the oscillations.

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Stereocenter

In a molecule, a stereocenter is a particular instance of a stereogenic element that is geometrically a point.

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Stereochemistry

Stereochemistry, a subdiscipline of chemistry, involves the study of the relative spatial arrangement of atoms that form the structure of molecules and their manipulation.

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Structural isomer

Structural isomerism, or constitutional isomerism (per IUPAC), is a form of isomerism in which molecules with the same molecular formula have different bonding patterns and atomic organization, as opposed to stereoisomerism, in which molecular bonds are always in the same order and only spatial arrangement differs.

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Transition state

The transition state of a chemical reaction is a particular configuration along the reaction coordinate.

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Van der Waals strain

In chemistry, van der Waals strain is strain resulting from van der Waals repulsion when two substituents in a molecule approach each other with a distance less than the sum of their van der Waals radii.

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Redirects here:

Configurational Isomer, Configurational isomer, Configurational stereoisomer, Stereo Isomers, Stereo isomer, Stereo-Isomerism, Stereoisomer, Stereoisomeric, Stereoisomers, Stereomer, Stereosiomer.

References

[1] https://en.wikipedia.org/wiki/Stereoisomerism

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