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Alkyne

Index Alkyne

In organic chemistry, an alkyne is an unsaturated hydrocarbon containing at least one carbon—carbon triple bond. [1]

127 relations: -ane, -yne, Acetophenone, Acetylene, Acetylide, Acid dissociation constant, Acrylate, Affix, Aldehyde, Alkene, Alkyne metathesis, Alkyne trimerisation, Alkyne zipper reaction, Alkynylation, Ammonia, Apiaceae, Aromaticity, Aryne, Asteraceae, Atomic orbital, Azide-alkyne Huisgen cycloaddition, Base (chemistry), Bergman cyclization, Bond energy, Bromine, Cadiot–Chodkiewicz coupling, Calicheamicin, Carbanion, Carbon dioxide, Carbon monoxide, Carbonyl group, Carbonylation, Carboxylic acid, Chemical nomenclature, Chrysanthemum, Cicuta, Cicutoxin, Conjugate acid, Conjugated system, Corey–Fuchs reaction, Coupling reaction, Cracking (chemistry), Cycloaddition, Cycloalkyne, Dehydrohalogenation, Diels–Alder reaction, Diene, Diphenylacetylene, Efavirenz, Electron, ..., Enol, Enyne metathesis, Ethanol, Falcarinol, Favorskii reaction, Fritsch–Buttenberg–Wiechell rearrangement, Functional group, Glaser coupling, Grignard reaction, Halide, Haloalkane, Halogen, Halogenation, Homologous series, Hydration reaction, Hydroboration–oxidation reaction, Hydrocarbon, Hydrogenation, Hydrohalogenation, Hyphen, Ichthyothere, Infix, Inorganic compound, IUPAC nomenclature of organic chemistry, Journal of Organic Chemistry, Keto–enol tautomerism, Ketone, Lindlar catalyst, Locant, Markovnikov's rule, Molecular geometry, Molecular orbital theory, N-Butyllithium, Natural gas, Nematicide, Noretynodrel, Nucleophile, Octyne, Oenanthotoxin, Oligomer, Orbital hybridisation, Organic chemistry, Organic reaction, Organic synthesis, Palladium, Pauson–Khand reaction, Phenylacetylene, Pi bond, Picometre, Polyacetylene, Polymerization, Polyyne, Potassium permanganate, Propargyl alcohol, Propyne, Ralph Raphael, Saturation (chemistry), Seyferth–Gilbert homologation, Sigma bond, Silver, Sodium amide, Sonogashira coupling, Styrene, Tariric acid, Terbinafine, Thiol-yne reaction, Tollens' reagent, Triazole, Triple bond, Valence bond theory, Vicinal (chemistry), Vinyl bromide, Vinyl halide, Water dropwort, 1,4-Cyclohexadiene, 2-Pyrone, 3-Hexyne. Expand index (77 more) »

-ane

The suffix -ane is used in organic chemistry to form names of organic compounds where the -C-C- group has been attributed the highest priority according to the rules of organic nomenclature.

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-yne

In chemistry, the suffix -yne is used to denote the presence of a triple bond.

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Acetophenone

Acetophenone is the organic compound with the formula C6H5C(O)CH3 (also represented by the pseudoelement symbols PhAc or BzMe).

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Acetylene

Acetylene (systematic name: ethyne) is the chemical compound with the formula C2H2.

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Acetylide

Acetylide refers to chemical compounds with the chemical formulas MC≡CH and MC≡CM, where M is a metal.

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Acid dissociation constant

An acid dissociation constant, Ka, (also known as acidity constant, or acid-ionization constant) is a quantitative measure of the strength of an acid in solution.

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Acrylate

Acrylates are the salts, esters, and conjugate bases of acrylic acid and its derivatives.

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Affix

In linguistics, an affix is a morpheme that is attached to a word stem to form a new word or word form.

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Aldehyde

An aldehyde or alkanal is an organic compound containing a functional group with the structure −CHO, consisting of a carbonyl center (a carbon double-bonded to oxygen) with the carbon atom also bonded to hydrogen and to an R group, which is any generic alkyl or side chain.

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Alkene

In organic chemistry, an alkene is an unsaturated hydrocarbon that contains at least one carbon–carbon double bond.

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Alkyne metathesis

Alkyne metathesis is an organic reaction involving the redistribution of alkyne chemical bonds.

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Alkyne trimerisation

An alkyne trimerisation reaction is a 2+2+2 cyclization reaction in which three molecules of alkyne react to form an arene.

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Alkyne zipper reaction

The alkyne zipper reaction is an organic reaction that involves isomerization of an internal alkyne into a terminal alkyne.

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Alkynylation

Alkynylation is an addition reaction in organic synthesis where a terminal alkyne adds to a carbonyl group to form an α-alkynyl alcohol.

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Ammonia

Ammonia is a compound of nitrogen and hydrogen with the formula NH3.

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Apiaceae

Apiaceae or Umbelliferae, is a family of mostly aromatic flowering plants named after the type genus Apium and commonly known as the celery, carrot or parsley family, or simply as umbellifers.

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Aromaticity

In organic chemistry, the term aromaticity is used to describe a cyclic (ring-shaped), planar (flat) molecule with a ring of resonance bonds that exhibits more stability than other geometric or connective arrangements with the same set of atoms.

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Aryne

Arynes or benzynes are highly reactive species derived from an aromatic ring by removal of two ortho substituents.

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Asteraceae

Asteraceae or Compositae (commonly referred to as the aster, daisy, composite,Great Basin Wildflowers, Laird R. Blackwell, 2006, p. 275 or sunflower family) is a very large and widespread family of flowering plants (Angiospermae).

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Atomic orbital

In quantum mechanics, an atomic orbital is a mathematical function that describes the wave-like behavior of either one electron or a pair of electrons in an atom.

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Azide-alkyne Huisgen cycloaddition

The azide-alkyne Huisgen cycloaddition is a 1,3-dipolar cycloaddition between an azide and a terminal or internal alkyne to give a 1,2,3-triazole.

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Base (chemistry)

In chemistry, bases are substances that, in aqueous solution, release hydroxide (OH−) ions, are slippery to the touch, can taste bitter if an alkali, change the color of indicators (e.g., turn red litmus paper blue), react with acids to form salts, promote certain chemical reactions (base catalysis), accept protons from any proton donor, and/or contain completely or partially displaceable OH− ions.

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Bergman cyclization

The Bergman cyclization or Bergman reaction or Bergman cycloaromatization is an organic reaction and more specifically a rearrangement reaction taking place when an enediyne is heated in presence of a suitable hydrogen donor (Scheme 1).

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Bond energy

In chemistry, bond energy (E) or bond enthalpy (H) is the measure of bond strength in a chemical bond.

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Bromine

Bromine is a chemical element with symbol Br and atomic number 35.

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Cadiot–Chodkiewicz coupling

The Cadiot–Chodkiewicz coupling in organic chemistry is a coupling reaction between a terminal alkyne and a haloalkyne catalyzed by a copper(I) salt such as copper(I) bromide and an amine base.

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Calicheamicin

The calicheamicins are a class of enediyne antitumor antibiotics derived from the bacterium Micromonospora echinospora, with calicheamicin γ1 being the most notable.

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Carbanion

A carbanion is an anion in which carbon is threevalent (forms three bonds) and bears a formal negative charge in at least one significant mesomeric contributor (resonance form).

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Carbon dioxide

Carbon dioxide (chemical formula) is a colorless gas with a density about 60% higher than that of dry air.

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Carbon monoxide

Carbon monoxide (CO) is a colorless, odorless, and tasteless gas that is slightly less dense than air.

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Carbonyl group

In organic chemistry, a carbonyl group is a functional group composed of a carbon atom double-bonded to an oxygen atom: C.

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Carbonylation

Carbonylation refers to reactions that introduce carbon monoxide into organic and inorganic substrates.

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Carboxylic acid

A carboxylic acid is an organic compound that contains a carboxyl group (C(.

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Chemical nomenclature

A chemical nomenclature is a set of rules to generate systematic names for chemical compounds.

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Chrysanthemum

Chrysanthemums, sometimes called mums or chrysanths, are flowering plants of the genus Chrysanthemum in the family Asteraceae.

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Cicuta

Cicuta, commonly known as water hemlock, is a small genus of four species of highly poisonous plants in the family Apiaceae.

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Cicutoxin

Cicutoxin is a poisonous polyyne and alcohol found in various plants, such as the highly toxic water hemlock (Cicuta species).

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Conjugate acid

A conjugate acid, within the Brønsted–Lowry acid–base theory, is a species formed by the reception of a proton (H+) by a base—in other words, it is a base with a hydrogen ion added to it.

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Conjugated system

In chemistry, a conjugated system is a system of connected p-orbitals with delocalized electrons in molecules which are conventionally represented as having alternating single and multiple bonds, which in general may lower the overall energy of the molecule and increase stability.

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Corey–Fuchs reaction

The Corey–Fuchs reaction, also known as the Ramirez–Corey–Fuchs reaction, is a series of chemical reactions designed to transform an aldehyde into an alkyne.

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Coupling reaction

A coupling reaction in organic chemistry is a general term for a variety of reactions where two hydrocarbon fragments are coupled with the aid of a metal catalyst.

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Cracking (chemistry)

In petrochemistry, petroleum geology and organic chemistry, cracking is the process whereby complex organic molecules such as kerogens or long-chain hydrocarbons are broken down into simpler molecules such as light hydrocarbons, by the breaking of carbon-carbon bonds in the precursors.

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Cycloaddition

A cycloaddition is a pericyclic chemical reaction, in which "two or more unsaturated molecules (or parts of the same molecule) combine with the formation of a cyclic adduct in which there is a net reduction of the bond multiplicity." The resulting reaction is a cyclization reaction.

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Cycloalkyne

In organic chemistry, a cycloalkyne is the cyclic analog of an alkyne.

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Dehydrohalogenation

Dehydrohalogenation is a chemical reaction that involves removal of (elimination of) a hydrogen halide from a substrate.

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Diels–Alder reaction

The Diels–Alder reaction is an organic chemical reaction (specifically, a cycloaddition) between a conjugated diene and a substituted alkene, commonly termed the dienophile, to form a substituted cyclohexene derivative.

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Diene

In organic chemistry a diene or diolefin is a hydrocarbon that contains two carbon double bonds.

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Diphenylacetylene

Diphenylacetylene is the chemical compound C6H5C≡CC6H5.

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Efavirenz

Efavirenz (EFV), sold under the brand names Sustiva among others, is an antiretroviral medication used to treat and prevent HIV/AIDS.

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Electron

The electron is a subatomic particle, symbol or, whose electric charge is negative one elementary charge.

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Enol

Enols, or more formally, alkenols, are a type of reactive structure or intermediate in organic chemistry that is represented as an alkene (olefin) with a hydroxyl group attached to one end of the alkene double bond.

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Enyne metathesis

An Enyne metathesis is an organic reaction taking place between an alkyne and an alkene with a metal carbene catalyst forming a butadiene.

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Ethanol

Ethanol, also called alcohol, ethyl alcohol, grain alcohol, and drinking alcohol, is a chemical compound, a simple alcohol with the chemical formula.

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Falcarinol

Falcarinol (also known as carotatoxin or panaxynol) is a natural pesticide and fatty alcohol found in carrots (Daucus carota), red ginseng (Panax ginseng) and ivy.

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Favorskii reaction

The Favorskii reaction is the nucleophilic attack of an acetylide on a carbonyl group.In fact this rearrangement is observed when alpha-halogenoketones are reacted with alkoxide bases(RO-) and forms carboxylic acids and/esters.

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Fritsch–Buttenberg–Wiechell rearrangement

The Fritsch–Buttenberg–Wiechell rearrangement, named for Paul Ernst Moritz Fritsch (1859–1913), Wilhelm Paul Buttenberg, and Heinrich G. Wiechell, is a chemical reaction whereby a 1,1-diaryl-2-bromo-alkene rearranges to a 1,2-diaryl-alkyne by reaction with a strong base such as an alkoxide.

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Functional group

In organic chemistry, functional groups are specific substituents or moieties within molecules that are responsible for the characteristic chemical reactions of those molecules.

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Glaser coupling

The Glaser coupling is a type of coupling reaction.

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Grignard reaction

The Grignard reaction (pronounced) is an organometallic chemical reaction in which alkyl, vinyl, or aryl-magnesium halides (Grignard reagents) add to a carbonyl group in an aldehyde or ketone.

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Halide

A halide is a binary phase, of which one part is a halogen atom and the other part is an element or radical that is less electronegative (or more electropositive) than the halogen, to make a fluoride, chloride, bromide, iodide, astatide, or theoretically tennesside compound.

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Haloalkane

The haloalkanes (also known as halogenoalkanes or alkyl halides) are a group of chemical compounds derived from alkanes containing one or more halogens.

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Halogen

The halogens are a group in the periodic table consisting of five chemically related elements: fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and astatine (At).

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Halogenation

Halogenation is a chemical reaction that involves the addition of one or more halogens to a compound or material.

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Homologous series

In organic chemistry, a homologous series is a series of compounds with the same functional group and similar chemical properties.

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Hydration reaction

In chemistry, a hydration reaction is a chemical reaction in which a substance combines with water.

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Hydroboration–oxidation reaction

In organic chemistry, the hydroboration–oxidation reaction is a two-step organic reaction that converts an alkene into a neutral alcohol by the net addition of water across the double bond.

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Hydrocarbon

In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon.

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Hydrogenation

Hydrogenation – to treat with hydrogen – is a chemical reaction between molecular hydrogen (H2) and another compound or element, usually in the presence of a catalyst such as nickel, palladium or platinum.

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Hydrohalogenation

A hydrohalogenation reaction is the electrophilic addition of hydrohalic acids like hydrogen chloride or hydrogen bromide to alkenes to yield the corresponding haloalkanes.

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Hyphen

The hyphen (‐) is a punctuation mark used to join words and to separate syllables of a single word.

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Ichthyothere

Ichthyothere is a genus of flowering plants, found in parts of South America (the Amazon) and Central America.

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Infix

An infix is an affix inserted inside a word stem (an existing word).

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Inorganic compound

An inorganic compound is typically a chemical compound that lacks C-H bonds, that is, a compound that is not an organic compound, but the distinction is not defined or even of particular interest.

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IUPAC nomenclature of organic chemistry

In chemical nomenclature, the IUPAC nomenclature of organic chemistry is a systematic method of naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC).

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Journal of Organic Chemistry

The Journal of Organic Chemistry, colloquially known as JOC or J Org, is a peer-reviewed scientific journal for original contributions of fundamental research in all branches of theory and practice in organic and bioorganic chemistry.

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Keto–enol tautomerism

In organic chemistry, keto–enol tautomerism refers to a chemical equilibrium between a keto form (a ketone or an aldehyde) and an enol (an alcohol).

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Ketone

In chemistry, a ketone (alkanone) is an organic compound with the structure RC(.

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Lindlar catalyst

A Lindlar catalyst is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate which is then poisoned with various forms of lead or sulphur.

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Locant

In organic chemistry, a locant is a figure to indicate the position of a functional group within a molecule.

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Markovnikov's rule

In organic chemistry, Markovnikov's rule or Markownikoff's rule describes the outcome of some addition reactions.

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Molecular geometry

Molecular geometry is the three-dimensional arrangement of the atoms that constitute a molecule.

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Molecular orbital theory

In chemistry, molecular orbital (MO) theory is a method for determining molecular structure in which electrons are not assigned to individual bonds between atoms, but are treated as moving under the influence of the nuclei in the whole molecule.

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N-Butyllithium

n-Butyllithium (abbreviated n-BuLi) is an organolithium reagent.

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Natural gas

Natural gas is a naturally occurring hydrocarbon gas mixture consisting primarily of methane, but commonly including varying amounts of other higher alkanes, and sometimes a small percentage of carbon dioxide, nitrogen, hydrogen sulfide, or helium.

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Nematicide

A nematicide is a type of chemical pesticide used to kill plant-parasitic nematodes.

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Noretynodrel

Noretynodrel, or norethynodrel, sold under the brand name Enovid among others, is a progestin medication which was previously used in birth control pills and in the treatment of gynecological disorders but is now no longer marketed. It was available both alone and in combination with an estrogen. The medication is taken by mouth. Noretynodrel is a progestin, or a synthetic progestogen, and hence is an agonist of the progesterone receptor, the biological target of progestogens like progesterone. It is a relatively weak progestogen. The medication has weak estrogenic activity, no or only very weak androgenic activity, and no other important hormonal activity. It is a prodrug of various active metabolites in the body, such as norethisterone among others. Noretynodrel was introduced for medical use in 1957. It was specifically approved at this time in combination with mestranol for the treatment of gynecological and menstrual disorders. Subsequently, in 1960, this formulation was approved for use as a birth control pill. It was the first birth control pill to be introduced, and was followed by birth control pills containing norethisterone and other progestins shortly thereafter. Due to its nature as a relatively weak progestogen, noretynodrel is no longer used in medicine. As such, it is no longer marketed.

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Nucleophile

Nucleophile is a chemical species that donates an electron pair to an electrophile to form a chemical bond in relation to a reaction.

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Octyne

The octynes are a subgroup from the group of alkynes.

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Oenanthotoxin

Oenanthotoxin is a toxin extracted from hemlock water dropwort (Oenanthe crocata) and other plants of the genus Oenanthe.

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Oligomer

An oligomer (oligo-, "a few" + -mer, "parts") is a molecular complex of chemicals that consists of a few monomer units, in contrast to a polymer, where the number of monomers is, in principle, infinite.

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Orbital hybridisation

In chemistry, orbital hybridisation (or hybridization) is the concept of mixing atomic orbitals into new hybrid orbitals (with different energies, shapes, etc., than the component atomic orbitals) suitable for the pairing of electrons to form chemical bonds in valence bond theory.

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Organic chemistry

Organic chemistry is a chemistry subdiscipline involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms.

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Organic reaction

Organic reactions are chemical reactions involving organic compounds.

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Organic synthesis

Organic synthesis is a special branch of chemical synthesis and is concerned with the intentional construction of organic compounds.

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Palladium

Palladium is a chemical element with symbol Pd and atomic number 46.

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Pauson–Khand reaction

The Pauson–Khand reaction (or PKR or PK-type reaction) is a chemical reaction described as a cycloaddition between an alkyne, an alkene and carbon monoxide to form a α,β-cyclopentenone.

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Phenylacetylene

Phenylacetylene is an alkyne hydrocarbon containing a phenyl group.

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Pi bond

In chemistry, pi bonds (π bonds) are covalent chemical bonds where two lobes of an orbital on one atom overlap two lobes of an orbital on another atom.

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Picometre

The picometre (international spelling as used by the International Bureau of Weights and Measures; SI symbol: pm) or picometer (American spelling) is a unit of length in the metric system, equal to, or one trillionth of a metre, which is the SI base unit of length.

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Polyacetylene

Polyacetylene (IUPAC name: polyethyne) usually refers to an organic polymer with the repeating unit (C2H2)n.

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Polymerization

In polymer chemistry, polymerization is a process of reacting monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks.

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Polyyne

In chemistry, a polyyne is any organic compound with alternating single and triple bonds; that is, a series of consecutive alkynes, with n greater than 1.

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Potassium permanganate

Potassium permanganate is an inorganic chemical compound and medication.

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Propargyl alcohol

Propargyl alcohol, or 2-propyn-1-ol, is an organic compound with the formula C3H4O.

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Propyne

Propyne (methylacetylene) is an alkyne with the chemical formula H3C≡CH.

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Ralph Raphael

Professor Ralph Alexander Raphael FRS CBE FRSE (1 January 1921 – 27 April 1998) was a British organic chemist, well known for his use of acteylene derivatives in the synthesis of natural products with biological activity.

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Saturation (chemistry)

In chemistry, saturation (from the Latin word saturare, meaning 'to fill') has diverse meanings, all based on the idea of reaching a maximum capacity.

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Seyferth–Gilbert homologation

The Seyferth–Gilbert homologation is a chemical reaction of an aryl ketone 1 (or aldehyde) with dimethyl (diazomethyl)phosphonate 2 and potassium tert-butoxide to give substituted alkynes 3.

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Sigma bond

In chemistry, sigma bonds (σ bonds) are the strongest type of covalent chemical bond.

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Silver

Silver is a chemical element with symbol Ag (from the Latin argentum, derived from the Proto-Indo-European ''h₂erǵ'': "shiny" or "white") and atomic number 47.

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Sodium amide

Sodium amide, commonly called sodamide, is the inorganic compound with the formula NaNH2.

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Sonogashira coupling

The Sonogashira reaction is a cross-coupling reaction used in organic synthesis to form carbon–carbon bonds.

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Styrene

Styrene, also known as ethenylbenzene, vinylbenzene, and phenylethene, is an organic compound with the chemical formula C6H5CH.

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Tariric acid

Tariric acid is an acetylenic fatty acid that can be found in the tallow-wood tree, Ximenia americana.

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Terbinafine

Terbinafine, sold under the brand name Lamisil among others, is an antifungal medication used to treat ringworm, pityriasis versicolor, and fungal nail infections.

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Thiol-yne reaction

The Thiol-yne reaction (also alkyne hydrothiolation) is an organic reaction between a thiol and an alkyne.

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Tollens' reagent

Tollens' reagent is a chemical reagent used to determine the presence of an aldehyde, aromatic aldehyde and alpha-hydroxy ketone functional groups.

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Triazole

A triazole refers to any of the heterocyclic compounds with molecular formula C2H3N3, having a five-membered ring of two carbon atoms and three nitrogen atoms.

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Triple bond

A triple bond in chemistry is a chemical bond between two atoms involving six bonding electrons instead of the usual two in a covalent single bond.

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Valence bond theory

In chemistry, valence bond (VB) theory is one of two basic theories, along with molecular orbital (MO) theory, that were developed to use the methods of quantum mechanics to explain chemical bonding.

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Vicinal (chemistry)

In chemistry the descriptor vicinal (from Latin vicinus.

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Vinyl bromide

Vinyl bromide is a simple vinyl halide.

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Vinyl halide

In organic chemistry, a vinyl halide is a compound with the formula CH2.

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Water dropwort

The water dropworts, Oenanthe, are a genus of plants in the family Apiaceae.

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1,4-Cyclohexadiene

1,4-Cyclohexadiene is an organic compound with the formula C6H8.

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2-Pyrone

2-Pyrone (α-pyrone or pyran-2-one) is an unsaturated cyclic chemical compound with the molecular formula C5H4O2.

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3-Hexyne

3-Hexyne is the organic compound with the formula C2H5CCC2H5, simplified to C6H10.

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Acetylene series, Acetylenes, Alkine, Alkyne hydration, Alkynes, Alkynyl, Carbon carbon triple bond, Carbon-carbon triple bond, Carbon–carbon triple bond, Terminal alkyne.

References

[1] https://en.wikipedia.org/wiki/Alkyne

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