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Chemical shift

Index Chemical shift

In nuclear magnetic resonance (NMR) spectroscopy, the chemical shift is the resonant frequency of a nucleus relative to a standard in a magnetic field. [1]

67 relations: Alkene, Alkyl, Alkyne, Anisotropy, Aromatic ring current, Aromaticity, Atomic nucleus, Benzene, Carbon-13 nuclear magnetic resonance, Clock rate, CRC Handbook of Chemistry and Physics, Cyclooctatetraene, Delta (letter), DNA, DSS (NMR standard), Electronegativity, Elementary charge, EuFOD, Fluorine-19 nuclear magnetic resonance spectroscopy, Frequency, Gamma, Gauss (unit), Gyromagnetic ratio, Haloalkane, Hertz, Hyperconjugation, Inductive effect, Infrared spectroscopy, Isotope, Journal of Chemical Education, Knight shift, Larmor precession, Lenz's law, Magnetic field, Magnetic moment, Magnetic resonance imaging, Mass spectrometry, Mössbauer spectroscopy, Molecule, Natural abundance, Nitro compound, Nuclear magnetic resonance, Nuclear magnetic resonance spectroscopy of carbohydrates, Nuclear magnetic resonance spectroscopy of nucleic acids, Nuclear magnetic resonance spectroscopy of proteins, Nuclear magneton, Omega, Parts-per notation, Photoemission spectroscopy, Pi bond, ..., Planck constant, Polar effect, Protein, Proton nuclear magnetic resonance, Pure and Applied Chemistry, Random coil index, Relaxation (NMR), Resonance, Solid-state nuclear magnetic resonance, Spin (physics), Spin quantum number, Tesla (unit), Tetramethylsilane, TRISPHAT, Tropylium cation, X-ray photoelectron spectroscopy, Zeeman effect. Expand index (17 more) »

Alkene

In organic chemistry, an alkene is an unsaturated hydrocarbon that contains at least one carbon–carbon double bond.

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Alkyl

In organic chemistry, an alkyl substituent is an alkane missing one hydrogen.

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Alkyne

In organic chemistry, an alkyne is an unsaturated hydrocarbon containing at least one carbon—carbon triple bond.

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Anisotropy

Anisotropy, is the property of being directionally dependent, which implies different properties in different directions, as opposed to isotropy.

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Aromatic ring current

An aromatic ring current is an effect observed in aromatic molecules such as benzene and naphthalene.

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Aromaticity

In organic chemistry, the term aromaticity is used to describe a cyclic (ring-shaped), planar (flat) molecule with a ring of resonance bonds that exhibits more stability than other geometric or connective arrangements with the same set of atoms.

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Atomic nucleus

The atomic nucleus is the small, dense region consisting of protons and neutrons at the center of an atom, discovered in 1911 by Ernest Rutherford based on the 1909 Geiger–Marsden gold foil experiment.

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Benzene

Benzene is an important organic chemical compound with the chemical formula C6H6.

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Carbon-13 nuclear magnetic resonance

Carbon-13 (C13)nuclear magnetic resonance (most commonly known as carbon-13 NMR or 13C NMR or sometimes simply referred to as carbon NMR) is the application of nuclear magnetic resonance (NMR) spectroscopy to carbon.

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Clock rate

The clock rate typically refers to the frequency at which a chip like a central processing unit (CPU), one core of a multi-core processor, is running and is used as an indicator of the processor's speed.

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CRC Handbook of Chemistry and Physics

The CRC Handbook of Chemistry and Physics is a comprehensive one-volume reference resource for science research, currently in its 98th edition (with 2560 pages, June 23, 2017, Editor-in-Chief John R. Rumble).

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Cyclooctatetraene

1,3,5,7-Cyclooctatetraene (COT) is an unsaturated derivative of cyclooctane, with the formula C8H8.

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Delta (letter)

Delta (uppercase Δ, lowercase δ or 𝛿; δέλτα délta) is the fourth letter of the Greek alphabet.

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DNA

Deoxyribonucleic acid (DNA) is a thread-like chain of nucleotides carrying the genetic instructions used in the growth, development, functioning and reproduction of all known living organisms and many viruses.

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DSS (NMR standard)

DSS (4,4-dimethyl-4-silapentane-1-sulfonic acid) is a chemical compound used in proton- and carbon-related NMR spectroscopy as a calibration standard, similar to tetramethylsilane (TMS), but with much higher water solubility.

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Electronegativity

Electronegativity, symbol ''χ'', is a chemical property that describes the tendency of an atom to attract a shared pair of electrons (or electron density) towards itself.

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Elementary charge

The elementary charge, usually denoted as or sometimes, is the electric charge carried by a single proton, or equivalently, the magnitude of the electric charge carried by a single electron, which has charge.

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EuFOD

EuFOD is the chemical compound with the formula Eu(OCC(CH3)3CHCOC3F7)3, also called Eu(fod)3.

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Fluorine-19 nuclear magnetic resonance spectroscopy

Fluorine-19 nuclear magnetic resonance spectroscopy (fluorine NMR or 19F NMR) is an analytical technique used to detect and identify fluorine-containing compounds.

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Frequency

Frequency is the number of occurrences of a repeating event per unit of time.

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Gamma

Gamma (uppercase, lowercase; gámma) is the third letter of the Greek alphabet.

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Gauss (unit)

The gauss, abbreviated as G or Gs, is the cgs unit of measurement of magnetic flux density (or "magnetic induction") (B).

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Gyromagnetic ratio

In physics, the gyromagnetic ratio (also sometimes known as the magnetogyric ratio in other disciplines) of a particle or system is the ratio of its magnetic moment to its angular momentum, and it is often denoted by the symbol γ, gamma.

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Haloalkane

The haloalkanes (also known as halogenoalkanes or alkyl halides) are a group of chemical compounds derived from alkanes containing one or more halogens.

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Hertz

The hertz (symbol: Hz) is the derived unit of frequency in the International System of Units (SI) and is defined as one cycle per second.

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Hyperconjugation

In organic chemistry, hyperconjugation is the interaction of the electrons in a sigma orbital (e.g. C–H or C–C) with an adjacent empty (or partially filled) non-bonding orbital, antibonding σ or π orbital, to give an extended molecular orbital.

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Inductive effect

In chemistry and physics, the inductive effect is an experimentally observed effect of the transmission of charge through a chain of atoms in a molecule, resulting in a permanent dipole in a bond.

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Infrared spectroscopy

Infrared spectroscopy (IR spectroscopy or vibrational spectroscopy) involves the interaction of infrared radiation with matter.

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Isotope

Isotopes are variants of a particular chemical element which differ in neutron number.

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Journal of Chemical Education

The Journal of Chemical Education is a monthly peer-reviewed academic journal available in both print and electronic versions.

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Knight shift

The Knight shift is a shift in the nuclear magnetic resonance frequency of a paramagnetic substance first published in 1949 by the UC Berkeley physicist Walter D. Knight.

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Larmor precession

In physics, Larmor precession (named after Joseph Larmor) is the precession of the magnetic moment of an object about an external magnetic field.

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Lenz's law

Lenz's law (pronounced), named after the physicist Heinrich Friedrich Emil Lenz who formulated it in 1834, states that the direction of current induced in a conductor by a changing magnetic field due to induction is such that it creates a magnetic field that opposes the change that produced it.

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Magnetic field

A magnetic field is a vector field that describes the magnetic influence of electrical currents and magnetized materials.

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Magnetic moment

The magnetic moment is a quantity that represents the magnetic strength and orientation of a magnet or other object that produces a magnetic field.

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Magnetic resonance imaging

Magnetic resonance imaging (MRI) is a medical imaging technique used in radiology to form pictures of the anatomy and the physiological processes of the body in both health and disease.

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Mass spectrometry

Mass spectrometry (MS) is an analytical technique that ionizes chemical species and sorts the ions based on their mass-to-charge ratio.

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Mössbauer spectroscopy

Mössbauer spectroscopy is a spectroscopic technique based on the Mössbauer effect.

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Molecule

A molecule is an electrically neutral group of two or more atoms held together by chemical bonds.

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Natural abundance

In physics, natural abundance (NA) refers to the abundance of isotopes of a chemical element as naturally found on a planet.

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Nitro compound

Nitro compounds are organic compounds that contain one or more nitro functional groups (−2).

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Nuclear magnetic resonance

Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a magnetic field absorb and re-emit electromagnetic radiation.

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Nuclear magnetic resonance spectroscopy of carbohydrates

Carbohydrate NMR Spectroscopy is the application of nuclear magnetic resonance (NMR) spectroscopy to structural and conformational analysis of carbohydrates.

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Nuclear magnetic resonance spectroscopy of nucleic acids

Nucleic acid NMR is the use of nuclear magnetic resonance spectroscopy to obtain information about the structure and dynamics of nucleic acid molecules, such as DNA or RNA.

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Nuclear magnetic resonance spectroscopy of proteins

Nuclear magnetic resonance spectroscopy of proteins (usually abbreviated protein NMR) is a field of structural biology in which NMR spectroscopy is used to obtain information about the structure and dynamics of proteins, and also nucleic acids, and their complexes.

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Nuclear magneton

The nuclear magneton (symbol μN), is a physical constant of magnetic moment, defined in SI units by: and in Gaussian CGS units by: where: In SI units, its value is approximately: In Gaussian CGS units, its value can be given in convenient units as The nuclear magneton is the natural unit for expressing magnetic dipole moments of heavy particles such as nucleons and atomic nuclei.

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Omega

Omega (capital: Ω, lowercase: ω; Greek ὦ, later ὦ μέγα, Modern Greek ωμέγα) is the 24th and last letter of the Greek alphabet.

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Parts-per notation

In science and engineering, the parts-per notation is a set of pseudo-units to describe small values of miscellaneous dimensionless quantities, e.g. mole fraction or mass fraction.

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Photoemission spectroscopy

Photoemission spectroscopy (PES), also known as photoelectron spectroscopy, refers to energy measurement of electrons emitted from solids, gases or liquids by the photoelectric effect, in order to determine the binding energies of electrons in a substance.

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Pi bond

In chemistry, pi bonds (π bonds) are covalent chemical bonds where two lobes of an orbital on one atom overlap two lobes of an orbital on another atom.

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Planck constant

The Planck constant (denoted, also called Planck's constant) is a physical constant that is the quantum of action, central in quantum mechanics.

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Polar effect

The polar effect or electronic effect in chemistry is the effect exerted by a substituent on modifying electrostatic forces operating on a nearby reaction center.

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Protein

Proteins are large biomolecules, or macromolecules, consisting of one or more long chains of amino acid residues.

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Proton nuclear magnetic resonance

Proton nuclear magnetic resonance (proton NMR, hydrogen-1 NMR, or 1H NMR) is the application of nuclear magnetic resonance in NMR spectroscopy with respect to hydrogen-1 nuclei within the molecules of a substance, in order to determine the structure of its molecules.

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Pure and Applied Chemistry

Pure and Applied Chemistry (abbreviated Pure Appl. Chem.) is the official journal for the International Union of Pure and Applied Chemistry (IUPAC).

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Random coil index

Random coil index (RCI) predicts protein flexibility by calculating an inverse weighted average of backbone secondary chemical shifts and predicting values of model-free order parameters as well as per-residue RMSD of NMR and molecular dynamics ensembles from this parameter.

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Relaxation (NMR)

In nuclear magnetic resonance (NMR) spectroscopy and magnetic resonance imaging (MRI) the term relaxation describes how signals change with time.

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Resonance

In physics, resonance is a phenomenon in which a vibrating system or external force drives another system to oscillate with greater amplitude at specific frequencies.

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Solid-state nuclear magnetic resonance

Solid-state NMR (SSNMR) spectroscopy is a kind of nuclear magnetic resonance (NMR) spectroscopy, characterized by the presence of anisotropic (directionally dependent) interactions.

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Spin (physics)

In quantum mechanics and particle physics, spin is an intrinsic form of angular momentum carried by elementary particles, composite particles (hadrons), and atomic nuclei.

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Spin quantum number

In atomic physics, the spin quantum number is a quantum number that parameterizes the intrinsic angular momentum (or spin angular momentum, or simply spin) of a given particle.

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Tesla (unit)

The tesla (symbol T) is a derived unit of magnetic flux density (informally, magnetic field strength) in the International System of Units.

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Tetramethylsilane

Tetramethylsilane (abbreviated as TMS) is the organosilicon compound with the formula Si(CH3)4.

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TRISPHAT

Tributylammonium TRISPHAT is an organic salt with the formula +. The anion features phosphorus(V) bonded to three tetrachlorocatecholate (C6Cl4O22−) ligands.

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Tropylium cation

In organic chemistry, the tropylium ion is an aromatic species with a formula of +. Its name derives from the molecule tropine (itself named for the molecule atropine).

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X-ray photoelectron spectroscopy

X-ray photoelectron spectroscopy (XPS) is a surface-sensitive quantitative spectroscopic technique that measures the elemental composition at the parts per thousand range, empirical formula, chemical state and electronic state of the elements that exist within a material.

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Zeeman effect

The Zeeman effect, named after the Dutch physicist Pieter Zeeman, is the effect of splitting a spectral line into several components in the presence of a static magnetic field.

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Redirects here:

Chemical Shift, Chemical shift anisotropy, Deshielding, Shielding (NMR).

References

[1] https://en.wikipedia.org/wiki/Chemical_shift

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