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Nitrogen inversion

Index Nitrogen inversion

In chemistry, nitrogen inversion is a fluxional process in nitrogen and amines, whereby the molecule "turns inside out". [1]

35 relations: Activation energy, Amine, Angewandte Chemie, Arsine, Aziridine, Carbanion, Chemistry, Chiral resolution, Chirality (chemistry), Energy level splitting, Fluxional molecule, Gibbs free energy, Hydroquinone, Joule per mole, Journal of the American Chemical Society, Kurt Mislow, Maser, Microwave spectroscopy, Molecular vibration, Molecule, Nitrogen, Oxygen, Phenol, Phosphine, Pyramidal inversion, Quantum tunnelling, Racemization, Sodium dithionite, Stereocenter, Stibine, Sulfoxide, Temperature, The Feynman Lectures on Physics, Transition state, Trigonal planar molecular geometry.

Activation energy

In chemistry and physics, activation energy is the energy which must be available to a chemical or nuclear system with potential reactants to result in: a chemical reaction, nuclear reaction, or other various other physical phenomena.

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Amine

In organic chemistry, amines are compounds and functional groups that contain a basic nitrogen atom with a lone pair.

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Angewandte Chemie

Angewandte Chemie (meaning "Applied Chemistry") is a weekly peer-reviewed scientific journal that is published by Wiley-VCH on behalf of the German Chemical Society (Gesellschaft Deutscher Chemiker).

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Arsine

Arsine is an inorganic compound with the formula AsH3.

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Aziridine

Aziridines are organic compounds containing the aziridine functional group, a three-membered heterocycle with one amine group (-NH-) and two methylene bridges (--). The parent compound is aziridine (or ethylene imine), with molecular formula.

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Carbanion

A carbanion is an anion in which carbon is threevalent (forms three bonds) and bears a formal negative charge in at least one significant mesomeric contributor (resonance form).

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Chemistry

Chemistry is the scientific discipline involved with compounds composed of atoms, i.e. elements, and molecules, i.e. combinations of atoms: their composition, structure, properties, behavior and the changes they undergo during a reaction with other compounds.

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Chiral resolution

Chiral resolution in stereochemistry is a process for the separation of racemic compounds into their enantiomers.

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Chirality (chemistry)

Chirality is a geometric property of some molecules and ions.

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Energy level splitting

In quantum physics, energy level splitting of a quantum system occurs when a degenerate energy level of two or more states is split because corresponding Hamiltonian's eigenvalues become different.

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Fluxional molecule

Fluxional molecules are molecules that undergo dynamics such that some or all of their atoms interchange between symmetry-equivalent positions.

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Gibbs free energy

In thermodynamics, the Gibbs free energy (IUPAC recommended name: Gibbs energy or Gibbs function; also known as free enthalpy to distinguish it from Helmholtz free energy) is a thermodynamic potential that can be used to calculate the maximum of reversible work that may be performed by a thermodynamic system at a constant temperature and pressure (isothermal, isobaric).

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Hydroquinone

Hydroquinone, also benzene-1,4-diol or quinol, is an aromatic organic compound that is a type of phenol, a derivative of benzene, having the chemical formula C6H4(OH)2.

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Joule per mole

The joule per mole (symbol: J·mole−1 or J/mol) is an SI derived unit of energy per amount of material.

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Journal of the American Chemical Society

The Journal of the American Chemical Society (also known as JACS) is a weekly peer-reviewed scientific journal that was established in 1879 by the American Chemical Society.

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Kurt Mislow

Kurt Martin Mislow (June 5, 1923 – October 5, 2017) was a German-born American organic chemist who specialized in stereochemistry.

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Maser

A maser (an acronym for "microwave amplification by stimulated emission of radiation") is a device that produces coherent electromagnetic waves through amplification by stimulated emission.

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Microwave spectroscopy

Microwave spectroscopy is the spectroscopy method that employs microwaves, i.e. electromagnetic radiation at GHz frequencies, for the study of matter.

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Molecular vibration

A molecular vibration occurs when atoms in a molecule are in periodic motion while the molecule as a whole has constant translational and rotational motion.

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Molecule

A molecule is an electrically neutral group of two or more atoms held together by chemical bonds.

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Nitrogen

Nitrogen is a chemical element with symbol N and atomic number 7.

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Oxygen

Oxygen is a chemical element with symbol O and atomic number 8.

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Phenol

Phenol, also known as phenolic acid, is an aromatic organic compound with the molecular formula C6H5OH.

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Phosphine

Phosphine (IUPAC name: phosphane) is the compound with the chemical formula PH3.

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Pyramidal inversion

In chemistry, pyramidal inversion is a fluxional process in compounds with a pyramidal molecule, such as ammonia (NH3) "turns inside out".

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Quantum tunnelling

Quantum tunnelling or tunneling (see spelling differences) is the quantum mechanical phenomenon where a particle tunnels through a barrier that it classically cannot surmount.

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Racemization

In chemistry, racemization is the conversion of an enantiomerically pure mixture (one where only one enantiomer is present) into a mixture where more than one of the enantiomers are present.

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Sodium dithionite

Sodium dithionite (also known as sodium hydrosulfite) is a white crystalline powder with a weak sulfurous odor.

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Stereocenter

In a molecule, a stereocenter is a particular instance of a stereogenic element that is geometrically a point.

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Stibine

Stibine is a chemical compound with the formula SbH3.

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Sulfoxide

A sulfoxide is a chemical compound containing a sulfinyl (SO) functional group attached to two carbon atoms.

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Temperature

Temperature is a physical quantity expressing hot and cold.

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The Feynman Lectures on Physics

The Feynman Lectures on Physics is a physics textbook based on some lectures by Richard P. Feynman, a Nobel laureate who has sometimes been called "The Great Explainer".

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Transition state

The transition state of a chemical reaction is a particular configuration along the reaction coordinate.

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Trigonal planar molecular geometry

In chemistry, trigonal planar is a molecular geometry model with one atom at the center and three atoms at the corners of an equilateral triangle, called peripheral atoms, all in one plane.

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Redirects here:

Amine inversion, Nitrogen flip.

References

[1] https://en.wikipedia.org/wiki/Nitrogen_inversion

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