11 relations: Anti-periplanar, Carbocation, Delocalized electron, Epimer, Hexafluoro-2-propanol, Neighbouring group participation, Nucleophilic substitution, Solvation, Solvolysis, Steric effects, 2-Norbornyl cation.
Anti-periplanar
Anti-periplanar is a term used in organic chemistry to describe the A–B–C–D bond angle in a molecule.
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Carbocation
A carbocation (/karbɔkətaɪː'jɔ̃/) is an ion with a positively charged carbon atom.
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Delocalized electron
In chemistry, delocalized electrons are electrons in a molecule, ion or solid metal that are not associated with a single atom or a covalent bond.
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Epimer
In stereochemistry, an epimer is one of a pair of stereoisomers.
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Hexafluoro-2-propanol
Hexafluoroisopropanol, commonly abbreviated HFIP, is the organic compound with the formula (CF3)2CHOH.
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Neighbouring group participation
Neighbouring group participation (NGP) (also known as anchimeric assistance) in organic chemistry has been defined by IUPAC as the interaction of a reaction centre with a lone pair of electrons in an atom or the electrons present in a sigma bond or pi bond contained within the parent molecule but not conjugated with the reaction centre.
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Nucleophilic substitution
In organic and inorganic chemistry, nucleophilic substitution is a fundamental class of reactions in which an electron rich nucleophile selectively bonds with or attacks the positive or partially positive charge of an atom or a group of atoms to replace a leaving group; the positive or partially positive atom is referred to as an electrophile.
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Solvation
Solvation describes the interaction of solvent with dissolved molecules.
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Solvolysis
Solvolysis is a type of nucleophilic substitution (SN1) /(SN2) or elimination, where the nucleophile is a solvent molecule.
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Steric effects
Steric effects are nonbonding interactions that influence the shape (conformation) and reactivity of ions and molecules.
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2-Norbornyl cation
In organic chemistry, the term 2-norbornyl cation (equivalent with 2-bicyclo-heptyl cation) describes one of the three carbocations formed from derivatives of norbornane.
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