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Organometallic chemistry

Index Organometallic chemistry

Organometallic chemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal, including alkaline, alkaline earth, and transition metals, and sometimes broadened to include metalloids like boron, silicon, and tin, as well. [1]

192 relations: Acetaldehyde, Acetic acid, Acetylacetone, Acetylide, Akira Suzuki (chemist), Alfred Stock, Alkene, Alkoxide, Alkynylation, Ammonia, Annalen der Physik, Aroma compound, Arsenic, Arsine, Arsphenamine, Associative substitution, Beta-Hydride elimination, Bioorganometallic chemistry, Boron, Bridging ligand, Buchwald–Hartwig amination, Cacodyl, Carbometalation, Carbon, Carbon monoxide, Carbon–hydrogen bond activation, Carbonylation, Cativa process, Charles Friedel, Chemical & Engineering News, Chemical bond, Chemical compound, Cobalt, Cobaltocene, Constrained geometry complex, Coordinate covalent bond, Coordination complex, Coordination polymer, Copper, Coupling reaction, Covalent bond, Cyclobutadieneiron tricarbonyl, Diethylzinc, Dimethylmagnesium, Dimethylzinc, Dorothy Hodgkin, Edward Frankland, Ei-ichi Negishi, Electron counting, Electron transfer, ..., Enol, Ernst Otto Fischer, Ethylene, Fat, Ferrocene, Fischer–Tropsch process, Food industry, Gasoline, Geoffrey Wilkinson, Gilman reagent, Giulio Natta, Grignard reaction, Group 2 organometallic chemistry, Heck reaction, Henry Gilman, Heteroatom, Heterogeneous catalysis, Homocysteine, Homogeneous catalysis, Hydrocyanation, Hydroformylation, Hydrogenation, Hydrometalation, Hydrosilylation, Infrared spectroscopy, Inorganic chemistry, Insertion reaction, Isolobal principle, James Crafts, Johann Jacob Diesbach, John Ulric Nef (chemist), John Wiley & Sons, Karl Barry Sharpless, Karl Ziegler, Kenichi Fukui, Ligand, Light-emitting diode, List of semiconductor materials, Lithium, Louis Claude Cadet de Gassicourt, Ludwig Mond, Margarine, Metal, Metal carbon dioxide complex, Metal carbonyl, Metal phosphine complex, Metallacycle, Metallocene, Metalorganic vapour phase epitaxy, Metalorganics, Methionine, Methionine synthase, Methyl group, Methylcobalamin, Methylcyclopentadienyl manganese tricarbonyl, Migratory insertion, Monsanto process, N-Butyllithium, Nickel tetracarbonyl, Nobel Prize in Chemistry, Nuclear magnetic resonance spectroscopy, Nucleophilic abstraction, Olefin metathesis, Organic chemistry, Organoaluminium chemistry, Organoarsenic chemistry, Organoboron chemistry, Organocadmium compound, Organochromium chemistry, Organocobalt chemistry, Organocopper compound, Organogallium chemistry, Organogermanium compound, Organogold chemistry, Organoiridium compound, Organoiron chemistry, Organolanthanide chemistry, Organolead compound, Organolithium reagent, Organomanganese chemistry, Organomercury, Organometallics, Organonickel, Organopalladium, Organoplatinum, Organoruthenium chemistry, Organosilicon, Organosilver chemistry, Organotin chemistry, Organotitanium compound, Organouranium chemistry, Organozinc compound, Oxford University Press, Oxidative addition, Paul Ehrlich, Paul Sabatier (chemist), Period 2 element, Period 3 element, Period 4 element, Period 5 element, Period 6 element, Period 7 element, Phosphine, Pi bond, Platinum, Platinum Metals Review, Prussian blue, Reductive elimination, Richard F. Heck, Richard R. Schrock, Roald Hoffmann, Robert H. Grubbs, Ryōji Noyori, Sandwich compound, Selenium, Shell higher olefin process, Sigma bond, Sigma-bond metathesis, Silicon, Sonogashira coupling, Suzuki reaction, Tetraethyllead, Transition metal, Transition metal alkene complex, Transition metal hydride, Transmetalation, Triethylborane, Trimethylaluminium, Trimethylgallium, Trimethylindium, Trimethylstibine, Tris(triphenylphosphine)rhodium carbonyl hydride, Victor Grignard, Vitamin B12, Wacker process, Walter Hieber, William Christopher Zeise, William Standish Knowles, Yves Chauvin, Zeise's salt, Ziegler–Natta catalyst, 18-electron rule. Expand index (142 more) »

Acetaldehyde

Acetaldehyde (systematic name ethanal) is an organic chemical compound with the formula CH3CHO, sometimes abbreviated by chemists as MeCHO (Me.

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Acetic acid

Acetic acid, systematically named ethanoic acid, is a colourless liquid organic compound with the chemical formula CH3COOH (also written as CH3CO2H or C2H4O2).

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Acetylacetone

Acetylacetone is an organic compound that exists in two tautomeric forms that interconvert rapidly and are treated as a single compound in most applications.

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Acetylide

Acetylide refers to chemical compounds with the chemical formulas MC≡CH and MC≡CM, where M is a metal.

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Akira Suzuki (chemist)

is a Japanese chemist and Nobel Prize Laureate (2010), who first published the Suzuki reaction, the organic reaction of an aryl- or vinyl-boronic acid with an aryl- or vinyl-halide catalyzed by a palladium(0) complex, in 1979.

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Alfred Stock

Alfred Stock (July 16, 1876 – August 12, 1946) was a German inorganic chemist.

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Alkene

In organic chemistry, an alkene is an unsaturated hydrocarbon that contains at least one carbon–carbon double bond.

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Alkoxide

An alkoxide is the conjugate base of an alcohol and therefore consists of an organic group bonded to a negatively charged oxygen atom.

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Alkynylation

Alkynylation is an addition reaction in organic synthesis where a terminal alkyne adds to a carbonyl group to form an α-alkynyl alcohol.

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Ammonia

Ammonia is a compound of nitrogen and hydrogen with the formula NH3.

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Annalen der Physik

Annalen der Physik (English: Annals of Physics) is one of the oldest scientific journals on physics and has been published since 1799.

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Aroma compound

An aroma compound, also known as an odorant, aroma, fragrance, or flavor, is a chemical compound that has a smell or odor.

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Arsenic

Arsenic is a chemical element with symbol As and atomic number 33.

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Arsine

Arsine is an inorganic compound with the formula AsH3.

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Arsphenamine

Arsphenamine, also known as Salvarsan or compound 606, is a drug that was introduced at the beginning of the 1910s as the first effective treatment for syphilis, and was also used to treat trypanosomiasis.

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Associative substitution

Associative substitution describes a pathway by which compounds interchange ligands.

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Beta-Hydride elimination

β-Hydride elimination is a reaction in which an alkyl group bonded to a metal centre is converted into the corresponding metal-bonded hydride and an alkene.

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Bioorganometallic chemistry

Bioorganometallic chemistry is the study of biologically active molecules that contain carbon directly bonded to metals or metalloids.

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Boron

Boron is a chemical element with symbol B and atomic number 5.

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Bridging ligand

In coordination chemistry, a bridging ligand is a ligand that connects two or more atoms, usually metal ions.

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Buchwald–Hartwig amination

The Buchwald–Hartwig amination is a chemical reaction used in organic chemistry for the synthesis of carbon–nitrogen bonds via the palladium-catalyzed cross-coupling of amines with aryl halides.

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Cacodyl

Cacodyl, also known as dicacodyl or tetramethyldiarsine, (CH3)2As—As(CH3)2, is an organoarsenic compound that constitutes a major part of "Cadet's fuming liquid" (named after the French chemist Louis Claude Cadet de Gassicourt).

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Carbometalation

Carbometalation (less often carbometallation) is an organometallic reaction involving the insertion of alkenes and alkynes into a metal-carbon bond.

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Carbon

Carbon (from carbo "coal") is a chemical element with symbol C and atomic number 6.

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Carbon monoxide

Carbon monoxide (CO) is a colorless, odorless, and tasteless gas that is slightly less dense than air.

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Carbon–hydrogen bond activation

Carbon–hydrogen bond functionalization (C–H functionalization) is a type of reaction in which a carbon–hydrogen bond is cleaved and replaced with a carbon-X bond (where X is usually carbon, oxygen, or nitrogen).

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Carbonylation

Carbonylation refers to reactions that introduce carbon monoxide into organic and inorganic substrates.

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Cativa process

The Cativa process is a method for the production of acetic acid by the carbonylation of methanol.

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Charles Friedel

Charles Friedel (12 March 1832 – 20 April 1899) was a French chemist and mineralogist.

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Chemical & Engineering News

Chemical & Engineering News (C&EN) is a weekly trade magazine published by the American Chemical Society, providing professional and technical information in the fields of chemistry and chemical engineering.

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Chemical bond

A chemical bond is a lasting attraction between atoms, ions or molecules that enables the formation of chemical compounds.

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Chemical compound

A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) composed of atoms from more than one element held together by chemical bonds.

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Cobalt

Cobalt is a chemical element with symbol Co and atomic number 27.

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Cobaltocene

Cobaltocene, known also as bis(cyclopentadienyl)cobalt(II) or even "bis Cp cobalt", is an organocobalt compound with the formula Co(C5H5)2.

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Constrained geometry complex

In organometallic chemistry, a "constrained geometry complex" (CGC) is a kind of catalyst used for the production of polyolefins such as polyethylene and polypropylene.

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Coordinate covalent bond

A coordinate covalent bond, also known as a dative bond or coordinate bond is a kind of 2-center, 2-electron covalent bond in which the two electrons derive from the same atom.

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Coordination complex

In chemistry, a coordination complex consists of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands or complexing agents.

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Coordination polymer

A coordination polymer is an inorganic or organometallic polymer structure containing metal cation centers linked by ligands.

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Copper

Copper is a chemical element with symbol Cu (from cuprum) and atomic number 29.

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Coupling reaction

A coupling reaction in organic chemistry is a general term for a variety of reactions where two hydrocarbon fragments are coupled with the aid of a metal catalyst.

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Covalent bond

A covalent bond, also called a molecular bond, is a chemical bond that involves the sharing of electron pairs between atoms.

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Cyclobutadieneiron tricarbonyl

Cyclobutadieneiron tricarbonyl or (C4H4)Fe(CO)3 is an organoiron compound with the formula Fe(C4H4)(CO)3.

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Diethylzinc

Diethylzinc (C2H5)2Zn, or DEZ, is a highly pyrophoric and reactive organozinc compound consisting of a zinc center bound to two ethyl groups.

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Dimethylmagnesium

Dimethylmagnesium is an organomagnesium compound.

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Dimethylzinc

Dimethylzinc, also known as Zinc methyl, DMZ, or DMZn is a colorless volatile liquid Zn(CH3)2, formed by the action of methyl iodide on zinc at elevated temperature or on zinc sodium alloy.

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Dorothy Hodgkin

Dorothy Mary Crowfoot Hodgkin (12 May 1910 – 29 July 1994) was a British chemist who developed protein crystallography, for which she won the Nobel Prize in Chemistry in 1964.

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Edward Frankland

Sir Edward Frankland, (18 January 1825 – 9 August 1899) was a British chemist.

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Ei-ichi Negishi

is a Manchurian-born Japanese chemist who has spent most of his career at Purdue University in the United States.

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Electron counting

Electron counting is a formalism used for classifying compounds and for explaining or predicting electronic structure and bonding.

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Electron transfer

Electron transfer (ET) occurs when an electron relocates from an atom or molecule to another such chemical entity.

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Enol

Enols, or more formally, alkenols, are a type of reactive structure or intermediate in organic chemistry that is represented as an alkene (olefin) with a hydroxyl group attached to one end of the alkene double bond.

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Ernst Otto Fischer

Ernst Otto Fischer (10 November 1918 – 23 July 2007) was a German chemist who won the Nobel Prize for pioneering work in the area of organometallic chemistry.

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Ethylene

Ethylene (IUPAC name: ethene) is a hydrocarbon which has the formula or H2C.

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Fat

Fat is one of the three main macronutrients, along with carbohydrate and protein.

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Ferrocene

Ferrocene is an organometallic compound with the formula Fe(C5H5)2.

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Fischer–Tropsch process

The Fischer–Tropsch process is a collection of chemical reactions that converts a mixture of carbon monoxide and hydrogen into liquid hydrocarbons.

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Food industry

The food industry is a complex, global collective of diverse businesses that supplies most of the food consumed by the world population.

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Gasoline

Gasoline (American English), or petrol (British English), is a transparent, petroleum-derived liquid that is used primarily as a fuel in spark-ignited internal combustion engines.

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Geoffrey Wilkinson

Sir Geoffrey Wilkinson FRS (14 July 1921 – 26 September 1996) was a Nobel laureate English chemist who pioneered inorganic chemistry and homogeneous transition metal catalysis.

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Gilman reagent

A Gilman reagent is a lithium and copper (diorganocopper) reagent compound, R2CuLi, where R is an alkyl or aryl.

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Giulio Natta

Giulio Natta (26 February 1903 – 2 May 1979) was an Italian chemist and Nobel laureate.

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Grignard reaction

The Grignard reaction (pronounced) is an organometallic chemical reaction in which alkyl, vinyl, or aryl-magnesium halides (Grignard reagents) add to a carbonyl group in an aldehyde or ketone.

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Group 2 organometallic chemistry

The group 2 elements are known to form organometallic compounds.

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Heck reaction

The Heck reaction (also called the Mizoroki-Heck reaction) is the chemical reaction of an unsaturated halide (or triflate) with an alkene in the presence of a base and a palladium catalyst (or palladium nanomaterial-based catalyst) to form a substituted alkene.

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Henry Gilman

Henry Gilman (May 9, 1893 – November 7, 1986) was an American organic chemist known as the father of organometallic chemistry, the field within which his most notable work was done.

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Heteroatom

In chemistry, a heteroatom (from Ancient Greek heteros, "different", + atomos, "uncut") is any atom that is not carbon or hydrogen.

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Heterogeneous catalysis

In chemistry, heterogeneous catalysis refers to the form of catalysis where the phase of the catalyst differs from that of the reactants.

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Homocysteine

Homocysteine is a non-proteinogenic α-amino acid.

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Homogeneous catalysis

In chemistry, homogeneous catalysis is catalysis in a solution by a soluble catalyst.

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Hydrocyanation

Hydrocyanation is, most fundamentally, the process whereby H+ and –CN ions are added to a molecular substrate.

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Hydroformylation

Hydroformylation, also known as oxo synthesis or oxo process, is an industrial process for the production of aldehydes from alkenes.

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Hydrogenation

Hydrogenation – to treat with hydrogen – is a chemical reaction between molecular hydrogen (H2) and another compound or element, usually in the presence of a catalyst such as nickel, palladium or platinum.

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Hydrometalation

Hydrometalation (hydrometallation) is a type of chemical reaction in organometallic chemistry in which a chemical compound with a hydrogen to metal bond (M-H, metal hydride) adds to compounds with an unsaturated bond like an alkene (RC.

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Hydrosilylation

Hydrosilylation, also called catalytic hydrosilation, describes the addition of Si-H bonds across unsaturated bonds.

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Infrared spectroscopy

Infrared spectroscopy (IR spectroscopy or vibrational spectroscopy) involves the interaction of infrared radiation with matter.

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Inorganic chemistry

Inorganic chemistry deals with the synthesis and behavior of inorganic and organometallic compounds.

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Insertion reaction

An insertion reaction is a chemical reaction where one chemical entity (a molecule or molecular fragment) interposes itself into an existing bond of typically a second chemical entity e.g.: The term only refers to the result of the reaction and does not suggest a mechanism.

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Isolobal principle

The isolobal principle (more formally known as the isolobal analogy) is a strategy used in organometallic chemistry to relate the structure of organic and inorganic molecular fragments in order to predict bonding properties of organometallic compounds.

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James Crafts

James Mason Crafts (March 8, 1839 – June 20, 1917) was an American chemist, mostly known for developing the Friedel-Crafts alkylation and acylation reactions with Charles Friedel in 1876.

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Johann Jacob Diesbach

Johann Jacob Diesbach was a Swiss pigment and dye producer known for first synthesizing a blue pigment known as Prussian blue (i.e. iron blue or Berlin blue).

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John Ulric Nef (chemist)

John Ulric Nef (Johann Ulrich Nef; June 14, 1862 – August 13, 1915) was a Swiss-born American chemist and the discoverer of the Nef reaction and Nef synthesis.

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John Wiley & Sons

John Wiley & Sons, Inc., also referred to as Wiley, is a global publishing company that specializes in academic publishing.

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Karl Barry Sharpless

Karl Barry Sharpless (born April 28, 1941) is an American chemist known for his work on stereoselective reactions.

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Karl Ziegler

Karl Waldemar Ziegler (November 26, 1898 – August 12, 1973) was a German chemist who won the Nobel Prize in Chemistry in 1963, with Giulio Natta, for work on polymers.

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Kenichi Fukui

Kenichi Fukui (福井 謙一 Fukui Ken'ichi, October 4, 1918 – January 9, 1998) was a Japanese chemist, known as the first Asian scientist to receive a chemistry Nobel Prize.

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Ligand

In coordination chemistry, a ligand is an ion or molecule (functional group) that binds to a central metal atom to form a coordination complex.

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Light-emitting diode

A light-emitting diode (LED) is a two-lead semiconductor light source.

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List of semiconductor materials

Semiconductor materials are nominally small band gap insulators.

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Lithium

Lithium (from lit) is a chemical element with symbol Li and atomic number 3.

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Louis Claude Cadet de Gassicourt

Louis Claude Cadet de Gassicourt (24 July 1731 – 17 October 1799) was a French chemist who synthesised the first organometalic compound.

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Ludwig Mond

Ludwig Mond (7 March 1839 – 11 December 1909) was a German-born chemist and industrialist who took British nationality.

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Margarine

Margarine is an imitation butter spread used for flavoring, baking, and cooking.

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Metal

A metal (from Greek μέταλλον métallon, "mine, quarry, metal") is a material (an element, compound, or alloy) that is typically hard when in solid state, opaque, shiny, and has good electrical and thermal conductivity.

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Metal carbon dioxide complex

Metal carbon dioxide complexes are coordination complexes that contain carbon dioxide ligands.

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Metal carbonyl

Metal carbonyls are coordination complexes of transition metals with carbon monoxide ligands.

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Metal phosphine complex

In chemistry phosphines are L-type ligands.

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Metallacycle

In organometallic chemistry, a metallacycle is a derivative of a carbocyclic compound wherein a metal has replaced at least one carbon center; this is to some extent similar to heterocycles.

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Metallocene

A metallocene is a compound typically consisting of two cyclopentadienyl anions (abbreviated Cp) bound to a metal center (M) in the oxidation state II, with the resulting general formula (C5H5)2M.

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Metalorganic vapour phase epitaxy

Metalorganic vapour phase epitaxy (MOVPE), also known as organometallic vapour phase epitaxy (OMVPE) or metalorganic chemical vapour deposition (MOCVD), is a chemical vapour deposition method used to produce single or polycrystalline thin films.

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Metalorganics

Metal-organic compounds (jargon: metalorganics, metallo-organics) are a class of chemical compounds that contain metals and organic ligands, which confer solubility in organic solvents or volatility.

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Methionine

Methionine (symbol Met or M) is an essential amino acid in humans.

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Methionine synthase

Methionine synthase also known as MS, MeSe, MetH is responsible for the regeneration of methionine from homocysteine.

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Methyl group

A methyl group is an alkyl derived from methane, containing one carbon atom bonded to three hydrogen atoms — CH3.

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Methylcobalamin

Methylcobalamin (mecobalamin, MeCbl, or MeB) is a cobalamin, a form of 12.

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Methylcyclopentadienyl manganese tricarbonyl

Methylcyclopentadienyl manganese tricarbonyl (MMT or MCMT) is an organomanganese compound with the formula (C5H4CH3)Mn(CO)3.

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Migratory insertion

A migratory insertion is a type of reaction in organometallic chemistry wherein two ligands on a metal complex combine.

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Monsanto process

The Monsanto process is an industrial method for the manufacture of acetic acid by catalytic carbonylation of methanol.

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N-Butyllithium

n-Butyllithium (abbreviated n-BuLi) is an organolithium reagent.

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Nickel tetracarbonyl

Nickel carbonyl (IUPAC name: tetracarbonylnickel) is the organonickel compound with the formula Ni(CO)4.

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Nobel Prize in Chemistry

The Nobel Prize in Chemistry (Nobelpriset i kemi) is awarded annually by the Royal Swedish Academy of Sciences to scientists in the various fields of chemistry.

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Nuclear magnetic resonance spectroscopy

Nuclear magnetic resonance spectroscopy, most commonly known as NMR spectroscopy or magnetic resonance spectroscopy (MRS), is a spectroscopic technique to observe local magnetic fields around atomic nuclei.

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Nucleophilic abstraction

Nucleophilic abstraction is a type of an organometallic reaction which can be defined as a nucleophilic attack on a ligand which causes part or all of the original ligand to be removed from the metal along with the nucleophile.

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Olefin metathesis

Olefin metathesis is an organic reaction that entails the redistribution of fragments of alkenes (olefins) by the scission and regeneration of carbon-carbon double bonds.

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Organic chemistry

Organic chemistry is a chemistry subdiscipline involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms.

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Organoaluminium chemistry

Organoaluminium chemistry is the study of compounds containing bonds between carbon and aluminium bond.

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Organoarsenic chemistry

Organoarsenic chemistry is the chemistry of compounds containing a chemical bond between arsenic and carbon.

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Organoboron chemistry

Organoborane or organoboron compounds are chemical compounds of boron and carbon that are organic derivatives of BH3, for example trialkyl boranes.

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Organocadmium compound

An organocadmium compound is an organometallic compound containing a carbon to cadmium chemical bond.

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Organochromium chemistry

Organochromium chemistry is a branch of organometallic chemistry that deals with organic compounds containing a chromium to carbon bond and their reactions.

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Organocobalt chemistry

Organocobalt chemistry is the chemistry of organometallic compounds containing a carbon to cobalt chemical bond.

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Organocopper compound

Organocopper compounds in organometallic chemistry contain carbon to copper chemical bonds.

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Organogallium chemistry

Organogallium chemistry is the chemistry of organometallic compounds containing a carbon to gallium (Ga) chemical bond.

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Organogermanium compound

Organogermanium compounds are organometallic compounds containing a carbon to germanium or hydrogen to germanium chemical bond.

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Organogold chemistry

Organogold chemistry is the study of compounds containing gold–carbon bonds.

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Organoiridium compound

Organoiridium chemistry is the chemistry of organometallic compounds containing a iridium-carbon chemical bond.

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Organoiron chemistry

Organoiron chemistry is the chemistry of iron compounds containing a carbon-to-iron chemical bond.

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Organolanthanide chemistry

Organolanthanide chemistry is the field of chemistry that studies compounds with a lanthanide-to-carbon bond.

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Organolead compound

Organolead compounds are chemical compounds containing a chemical bond between carbon and lead.

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Organolithium reagent

Organolithium reagents are organometallic compounds that contain carbon – lithium bonds.

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Organomanganese chemistry

Organomanganese chemistry is the chemistry of organometallic compounds containing a carbon to manganese chemical bond.

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Organomercury

Organomercury refers to the group of organometallic compounds that contain mercury.

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Organometallics

Organometallics is a biweekly journal published by the American Chemical Society.

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Organonickel

Organonickel chemistry is a branch of organometallic chemistry that deals with organic compounds featuring nickel-carbon bonds.

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Organopalladium

Organopalladium chemistry is a branch of organometallic chemistry that deals with organic palladium compounds and their reactions.

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Organoplatinum

Organoplatinum chemistry is the chemistry of organometallic compounds containing a carbon to platinum chemical bond, and the study of platinum as a catalyst in organic reactions.

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Organoruthenium chemistry

Organoruthenium chemistry is the chemistry of organometallic compounds containing a carbon to ruthenium chemical bond.

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Organosilicon

Organosilicon compounds are organometallic compounds containing carbon–silicon bonds.

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Organosilver chemistry

Organosilver chemistry in chemistry is the study of organometallic compounds containing a carbon to silver chemical bond and the study of silver as catalyst in organic reactions.

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Organotin chemistry

Organotin compounds or stannanes are chemical compounds based on tin with hydrocarbon substituents.

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Organotitanium compound

Organotitanium compounds in organometallic chemistry contain carbon-to-titanium chemical bonds.

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Organouranium chemistry

Organouranium chemistry is the science exploring the properties, structure and reactivity of organouranium compounds, which are organometallic compounds containing a carbon to uranium chemical bond.

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Organozinc compound

Organozinc compounds in organic chemistry contain carbon to zinc chemical bonds.

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Oxford University Press

Oxford University Press (OUP) is the largest university press in the world, and the second oldest after Cambridge University Press.

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Oxidative addition

Oxidative addition and reductive elimination are two important and related classes of reactions in organometallic chemistry.

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Paul Ehrlich

Paul Ehrlich (14 March 1854 – 20 August 1915) was a German Jewish physician and scientist who worked in the fields of hematology, immunology, and antimicrobial chemotherapy.

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Paul Sabatier (chemist)

Prof Paul Sabatier FRS(For) HFRSE (5 November 1854 – 14 August 1941) was a French chemist, born in Carcassonne.

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Period 2 element

A period 2 element is one of the chemical elements in the second row (or period) of the periodic table of the chemical elements.

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Period 3 element

A period 3 element is one of the chemical elements in the third row (or period) of the periodic table of the chemical elements.

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Period 4 element

A period 4 element is one of the chemical elements in the fourth row (or period) of the periodic table of the elements.

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Period 5 element

A period 5 element is one of the chemical elements in the fifth row (or period) of the periodic table of the elements.

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Period 6 element

A period 6 element is one of the chemical elements in the sixth row (or period) of the periodic table of the elements, including the lanthanides.

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Period 7 element

A period 7 element is one of the chemical elements in the seventh row (or period) of the periodic table of the chemical elements.

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Phosphine

Phosphine (IUPAC name: phosphane) is the compound with the chemical formula PH3.

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Pi bond

In chemistry, pi bonds (π bonds) are covalent chemical bonds where two lobes of an orbital on one atom overlap two lobes of an orbital on another atom.

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Platinum

Platinum is a chemical element with symbol Pt and atomic number 78.

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Platinum Metals Review

Platinum Metals Review, renamed in 2014 as Johnson Matthey Technology Review, is a quarterly, peer-reviewed scientific journal publishing reports on scientific research on the platinum group metals and related industrial developments.

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Prussian blue

Prussian blue is a dark blue pigment produced by oxidation of ferrous ferrocyanide salts.

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Reductive elimination

Reductive elimination is an elementary step in organometallic chemistry in which the oxidation state of the metal center decreases while forming a new covalent bond between two ligands.

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Richard F. Heck

Richard Frederick Heck (August 15, 1931 – October 10, 2015) was an American chemist noted for the discovery and development of the Heck reaction, which uses palladium to catalyze organic chemical reactions that couple aryl halides with alkenes.

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Richard R. Schrock

Richard Royce Schrock (born January 4, 1945) is an American chemist and Nobel laureate recognized for his contributions to the olefin metathesis reaction used in organic chemistry.

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Roald Hoffmann

Roald Hoffmann (born Roald Safran; July 18, 1937) is a Polish-American theoretical chemist who won the 1981 Nobel Prize in Chemistry.

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Robert H. Grubbs

Robert Howard Grubbs (born February 27, 1942) is an American chemist and the Victor and Elizabeth Atkins Professor of Chemistry at the California Institute of Technology in Southern California.

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Ryōji Noyori

is a Japanese chemist.

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Sandwich compound

In organometallic chemistry, a sandwich compound is a chemical compound featuring a metal bound by haptic covalent bonds to two arene ligands.

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Selenium

Selenium is a chemical element with symbol Se and atomic number 34.

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Shell higher olefin process

The Shell higher olefin process is a chemical process for the production of linear alpha olefins via ethylene oligomerization and olefin metathesis invented and exploited by Royal Dutch Shell.

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Sigma bond

In chemistry, sigma bonds (σ bonds) are the strongest type of covalent chemical bond.

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Sigma-bond metathesis

In organometallic chemistry, sigma-bond metathesis is a chemical reaction.

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Silicon

Silicon is a chemical element with symbol Si and atomic number 14.

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Sonogashira coupling

The Sonogashira reaction is a cross-coupling reaction used in organic synthesis to form carbon–carbon bonds.

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Suzuki reaction

The Suzuki reaction is an organic reaction, classified as a coupling reaction, where the coupling partners are a boronic acid and an organohalide catalyzed by a palladium(0) complex.

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Tetraethyllead

Tetraethyllead (commonly styled tetraethyl lead), abbreviated TEL, is an organolead compound with the formula (CH3CH2)4Pb.

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Transition metal

In chemistry, the term transition metal (or transition element) has three possible meanings.

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Transition metal alkene complex

In organometallic chemistry, a transition metal alkene complex is a coordination compound containing one or more alkene ligands.

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Transition metal hydride

Transition metal hydrides are chemical compounds containing a transition metal bonded to hydrogen.

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Transmetalation

Transmetalation (alt. spelling: transmetallation) is a type of organometallic reaction that involves the transfer of ligands from one metal to another.

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Triethylborane

No description.

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Trimethylaluminium

Trimethylaluminium is one of the simplest examples of an organoaluminium compound.

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Trimethylgallium

Trimethylgallium, Ga(CH3)3, often abbreviated to TMG or TMGa, is the preferred metalorganic source of gallium for metalorganic vapour phase epitaxy (MOVPE) of gallium-containing compound semiconductors, such as GaAs, GaN, GaP, GaSb, InGaAs, InGaN, AlGaInP, InGaP and AlInGaNP.

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Trimethylindium

Trimethylindium (abbr: TMI or TMIn), In(CH3)3, (CAS #: 3385-78-2) is the preferred organometallic source of indium for metalorganic vapour phase epitaxy (MOVPE) of indium-containing compound semiconductors, such as InP, InAs, InN, InSb, GaInAs, InGaN, AlGaInP, AlInP, AlInGaNP, etc.

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Trimethylstibine

Trimethylstibine is an organoantimony compound with the formula Sb(CH3)3.

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Tris(triphenylphosphine)rhodium carbonyl hydride

Tris(triphenylphosphine)rhodium carbonyl hydride is an organorhodium compound with the formula (Ph.

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Victor Grignard

François Auguste Victor Grignard (6 May 1871 in Cherbourg – 13 December 1935 in Lyon) was a Nobel Prize-winning French chemist.

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Vitamin B12

Vitamin B12, also called cobalamin, is a water-soluble vitamin that is involved in the metabolism of every cell of the human body: it is a cofactor in DNA synthesis, and in both fatty acid and amino acid metabolism.

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Wacker process

The Wacker process or the Hoechst-Wacker process (named after the chemical companies of the same name) refers to the oxidation of ethylene to acetaldehyde in the presence of palladium(II) chloride as the catalyst.

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Walter Hieber

Walter Hieber (18 December 1895 – 29 November 1976) was an inorganic chemist, known as the father of metal carbonyl chemistry.

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William Christopher Zeise

William Christopher Zeise (October 15, 1789 – November 12, 1847) was a prominent early Danish organic chemist.

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William Standish Knowles

William Standish Knowles (June 1, 1917 – June 13, 2012) was an American chemist.

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Yves Chauvin

Yves Chauvin (10 October 1930 – 27 January 2015) was a French chemist and Nobel Prize laureate.

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Zeise's salt

Zeise's salt, potassium trichloro(ethene)platinate(II), is the chemical compound with the formula K·H2O.

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Ziegler–Natta catalyst

A Ziegler–Natta catalyst, named after Karl Ziegler and Giulio Natta, is a catalyst used in the synthesis of polymers of 1-alkenes (alpha-olefins).

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18-electron rule

The 18-electron rule is a rule used primarily for predicting and rationalizing formulae for stable metal complexes, especially organometallic compounds.

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References

[1] https://en.wikipedia.org/wiki/Organometallic_chemistry

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