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Paternò–Büchi reaction

Index Paternò–Büchi reaction

The Paternò–Büchi reaction, named after Emanuele Paternò and George Büchi who established its basic utility and form, is a photochemical reaction that forms four-membered oxetane rings from a carbonyl and an alkene. [1]

11 relations: Alkene, Benzaldehyde, Carbonyl group, Emanuele Paternò, Furan, George Büchi, Journal of the American Chemical Society, Mechanistic organic photochemistry, Oxetane, Structural isomer, 2-Methyl-2-butene.

Alkene

In organic chemistry, an alkene is an unsaturated hydrocarbon that contains at least one carbon–carbon double bond.

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Benzaldehyde

Benzaldehyde (C6H5CHO) is an organic compound consisting of a benzene ring with a formyl substituent.

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Carbonyl group

In organic chemistry, a carbonyl group is a functional group composed of a carbon atom double-bonded to an oxygen atom: C.

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Emanuele Paternò

Emanuele Paternò di Sessa was an Italian chemist, discoverer of the Paternò–Büchi reaction.

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Furan

Furan is a heterocyclic organic compound, consisting of a five-membered aromatic ring with four carbon atoms and one oxygen.

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George Büchi

George Hermann Büchi (August 1, 1921 – August 28, 1998) was organic chemist and professor at the Massachusetts Institute of Technology.

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Journal of the American Chemical Society

The Journal of the American Chemical Society (also known as JACS) is a weekly peer-reviewed scientific journal that was established in 1879 by the American Chemical Society.

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Mechanistic organic photochemistry

Mechanistic organic photochemistry is that aspect of organic photochemistry which seeks to explain the mechanisms of organic photochemical reactions.

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Oxetane

Oxetane, or 1,3-propylene oxide, is an heterocyclic organic compound with the molecular formula, having a four-membered ring with three carbon atoms and one oxygen atom.

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Structural isomer

Structural isomerism, or constitutional isomerism (per IUPAC), is a form of isomerism in which molecules with the same molecular formula have different bonding patterns and atomic organization, as opposed to stereoisomerism, in which molecular bonds are always in the same order and only spatial arrangement differs.

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2-Methyl-2-butene

2-Methyl-2-butene, 2m2b, 2-methylbut-2-ene, also amylene is an alkene hydrocarbon with the molecular formula C5H10.

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References

[1] https://en.wikipedia.org/wiki/Paternò–Büchi_reaction

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