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Reactions of organocopper reagents

Index Reactions of organocopper reagents

Reactions of organocopper reagents involve species containing copper-carbon bonds acting as nucleophiles in the presence of organic electrophiles. [1]

25 relations: Acetylene, Alkene, Alkylation, Allene, Boron trifluoride, Chemical species, Copper(I) cyanide, Double bond, Electrophile, Enantiomer, Epoxide, Gilman reagent, Grignard reaction, Ketone, Lewis acids and bases, Magnesium, Magnesium bromide, Nucleophile, Organic Reactions, Organic synthesis, Organolithium reagent, Pheromone, Racemization, Stoichiometry, Yoshito Kishi.

Acetylene

Acetylene (systematic name: ethyne) is the chemical compound with the formula C2H2.

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Alkene

In organic chemistry, an alkene is an unsaturated hydrocarbon that contains at least one carbon–carbon double bond.

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Alkylation

Alkylation is the transfer of an alkyl group from one molecule to another.

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Allene

An allene is a compound in which one carbon atom has double bonds with each of its two adjacent carbon centres.

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Boron trifluoride

Boron trifluoride is the inorganic compound with the formula BF3.

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Chemical species

A chemical species is a chemical substance or ensemble composed of chemically identical molecular entities that can explore the same set of molecular energy levels on a characteristic or delineated time scale.

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Copper(I) cyanide

Copper(I) cyanide is an inorganic compound with the formula CuCN.

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Double bond

A double bond in chemistry is a chemical bond between two chemical elements involving four bonding electrons instead of the usual two.

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Electrophile

In organic chemistry, an electrophile is a reagent attracted to electrons.

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Enantiomer

In chemistry, an enantiomer, also known as an optical isomer (and archaically termed antipode or optical antipode), is one of two stereoisomers that are mirror images of each other that are non-superposable (not identical), much as one's left and right hands are the same except for being reversed along one axis (the hands cannot be made to appear identical simply by reorientation).

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Epoxide

An epoxide is a cyclic ether with a three-atom ring.

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Gilman reagent

A Gilman reagent is a lithium and copper (diorganocopper) reagent compound, R2CuLi, where R is an alkyl or aryl.

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Grignard reaction

The Grignard reaction (pronounced) is an organometallic chemical reaction in which alkyl, vinyl, or aryl-magnesium halides (Grignard reagents) add to a carbonyl group in an aldehyde or ketone.

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Ketone

In chemistry, a ketone (alkanone) is an organic compound with the structure RC(.

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Lewis acids and bases

A Lewis acid is a chemical species that contains an empty orbital which is capable of accepting an electron pair from a Lewis base to form a Lewis adduct.

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Magnesium

Magnesium is a chemical element with symbol Mg and atomic number 12.

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Magnesium bromide

Magnesium bromide (MgBr2) is a chemical compound of magnesium and bromine that is white and deliquescent.

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Nucleophile

Nucleophile is a chemical species that donates an electron pair to an electrophile to form a chemical bond in relation to a reaction.

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Organic Reactions

Organic Reactions is a secondary reference which synthesizes the organic chemistry literature around particular chemical transformations.

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Organic synthesis

Organic synthesis is a special branch of chemical synthesis and is concerned with the intentional construction of organic compounds.

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Organolithium reagent

Organolithium reagents are organometallic compounds that contain carbon – lithium bonds.

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Pheromone

A pheromone (from Ancient Greek φέρω phero "to bear" and hormone, from Ancient Greek ὁρμή "impetus") is a secreted or excreted chemical factor that triggers a social response in members of the same species.

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Racemization

In chemistry, racemization is the conversion of an enantiomerically pure mixture (one where only one enantiomer is present) into a mixture where more than one of the enantiomers are present.

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Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions.

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Yoshito Kishi

is the Morris Loeb Professor of Chemistry at Harvard University.

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References

[1] https://en.wikipedia.org/wiki/Reactions_of_organocopper_reagents

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