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Star-shaped polymer

Index Star-shaped polymer

Star-shaped polymers are the simplest class of branched polymers with a general structure consisting of several (more than three) linear chains connected to a central core. [1]

64 relations: Alkene, Anionic addition polymerization, Atom, Biomedical engineering, Branching (polymer chemistry), Carbanion, Catalysis, Chemical structure, Chlorine, Chlorosilane, Copolymer, Critical micelle concentration, Crystallinity, Crystallization of polymers, Dispersity, Divinylbenzene, Doxorubicin, Drug delivery, Dynamic mechanical analysis, Electrophilic aromatic directing groups, Electrophilic substitution, Emulsion, Ethylene oxide, Gel, Gelation, Homogeneity and heterogeneity, Hydrodynamic radius, Internal combustion engine, Ion, Leaving group, Living anionic polymerization, Living cationic polymerization, Living free-radical polymerization, Living polymerization, Lubricant, Macromolecule, Maurice Morton, Melting point, Micelle, Molecular mass, Molecule, Nanoelectronics, Paul Flory, PH, Photoresist, Polyamide, Polymer, Radius of gyration, Rheology, Ring-opening metathesis polymerisation, ..., Ring-opening polymerization, Self-assembly, Size-exclusion chromatography, Sol–gel process, Solubility, Solvent, Static light scattering, Stoichiometry, Supramolecular chemistry, Telechelic polymer, Temperature, Thermoplastic elastomer, Viscosity, Viscosity index. Expand index (14 more) »

Alkene

In organic chemistry, an alkene is an unsaturated hydrocarbon that contains at least one carbon–carbon double bond.

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Anionic addition polymerization

Anionic addition polymerization is a form of chain-growth polymerization or addition polymerization that involves the polymerization of vinyl monomers with strong electronegative groups.

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Atom

An atom is the smallest constituent unit of ordinary matter that has the properties of a chemical element.

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Biomedical engineering

Biomedical engineering (BME) is the application of engineering principles and design concepts to medicine and biology for healthcare purposes (e.g. diagnostic or therapeutic).

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Branching (polymer chemistry)

In polymer chemistry, branching occurs by the replacement of a substituent, e.g., a hydrogen atom, on a monomer subunit, by another covalently bonded chain of that polymer; or, in the case of a graft copolymer, by a chain of another type.

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Carbanion

A carbanion is an anion in which carbon is threevalent (forms three bonds) and bears a formal negative charge in at least one significant mesomeric contributor (resonance form).

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Catalysis

Catalysis is the increase in the rate of a chemical reaction due to the participation of an additional substance called a catalysthttp://goldbook.iupac.org/C00876.html, which is not consumed in the catalyzed reaction and can continue to act repeatedly.

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Chemical structure

A chemical structure determination includes a chemist's specifying the molecular geometry and, when feasible and necessary, the electronic structure of the target molecule or other solid.

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Chlorine

Chlorine is a chemical element with symbol Cl and atomic number 17.

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Chlorosilane

Chlorosilanes are a group of reactive, chlorine-containing chemical compounds, related to silane and used in many chemical processes.

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Copolymer

When two or more different monomers unite together to polymerize, the product is called a copolymer and the process is called copolymerization.

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Critical micelle concentration

In colloidal and surface chemistry, the critical micelle concentration (CMC) is defined as the concentration of surfactants above which micelles form and all additional surfactants added to the system go to micelles.

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Crystallinity

Crystallinity refers to the degree of structural order in a solid.

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Crystallization of polymers

Crystallization of polymers is a process associated with partial alignment of their molecular chains.

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Dispersity

A monodisperse, or uniform, polymer is composed of molecules of the same mass.

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Divinylbenzene

Divinylbenzene (DVB) consists of a benzene ring bonded to two vinyl groups.

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Doxorubicin

Doxorubicin, sold under the trade names Adriamycin among others, is a chemotherapy medication used to treat cancer.

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Drug delivery

Drug delivery refers to approaches, formulations, technologies, and systems for transporting a pharmaceutical compound in the body as needed to safely achieve its desired therapeutic effect.

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Dynamic mechanical analysis

Dynamic mechanical analysis (abbreviated DMA, also known as dynamic mechanical spectroscopy) is a technique used to study and characterize materials.

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Electrophilic aromatic directing groups

In organic chemistry, an electron donating group (EDG) or electron releasing group (ERG) (+I effect) is an atom or functional group that donates some of its electron density into a conjugated π system via resonance or inductive effects, thus making the π system more nucleophilic.

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Electrophilic substitution

Electrophilic substitution reactions are chemical reactions in which an electrophile displaces a functional group in a compound, which is typically, but not always, a hydrogen atom.

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Emulsion

An emulsion is a mixture of two or more liquids that are normally immiscible (unmixable or unblendable).

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Ethylene oxide

Ethylene oxide, called oxirane by IUPAC, is an organic compound with the formula. It is a cyclic ether and the simplest epoxide: a three-membered ring consisting of one oxygen atom and two carbon atoms. Ethylene oxide is a colorless and flammable gas with a faintly sweet odor. Because it is a strained ring, ethylene oxide easily participates in a number of addition reactions that result in ring-opening. Ethylene oxide is isomeric with acetaldehyde and with vinyl alcohol. Ethylene oxide is industrially produced by oxidation of ethylene in the presence of silver catalyst. The reactivity that is responsible for many of ethylene oxide's hazards also make it useful. Although too dangerous for direct household use and generally unfamiliar to consumers, ethylene oxide is used for making many consumer products as well as non-consumer chemicals and intermediates. These products include detergents, thickeners, solvents, plastics, and various organic chemicals such as ethylene glycol, ethanolamines, simple and complex glycols, polyglycol ethers, and other compounds. Although it is a vital raw material with diverse applications, including the manufacture of products like polysorbate 20 and polyethylene glycol (PEG) that are often more effective and less toxic than alternative materials, ethylene oxide itself is a very hazardous substance. At room temperature it is a flammable, carcinogenic, mutagenic, irritating, and anaesthetic gas. As a toxic gas that leaves no residue on items it contacts, ethylene oxide is a surface disinfectant that is widely used in hospitals and the medical equipment industry to replace steam in the sterilization of heat-sensitive tools and equipment, such as disposable plastic syringes. It is so flammable and extremely explosive that it is used as a main component of thermobaric weapons; therefore, it is commonly handled and shipped as a refrigerated liquid to control its hazardous nature.Rebsdat, Siegfried and Mayer, Dieter (2005) "Ethylene Oxide" in Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH, Weinheim..

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Gel

A gel is a solid jelly-like material that can have properties ranging from soft and weak to hard and tough.

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Gelation

Gelation (gel transition) is the formation of a gel from a system with branched polymers.

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Homogeneity and heterogeneity

Homogeneity and heterogeneity are concepts often used in the sciences and statistics relating to the uniformity in a substance or organism.

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Hydrodynamic radius

The hydrodynamic radius of a macromolecule or colloid particle is R_.

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Internal combustion engine

An internal combustion engine (ICE) is a heat engine where the combustion of a fuel occurs with an oxidizer (usually air) in a combustion chamber that is an integral part of the working fluid flow circuit.

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Ion

An ion is an atom or molecule that has a non-zero net electrical charge (its total number of electrons is not equal to its total number of protons).

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Leaving group

In chemistry, a leaving group is a molecular fragment that departs with a pair of electrons in heterolytic bond cleavage.

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Living anionic polymerization

Living anionic polymerization is a living polymerization technique involving an anionic propagating species.

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Living cationic polymerization

Living cationic polymerization is a living polymerization technique involving cationic propagating species.

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Living free-radical polymerization

Living free radical polymerization is a type of living polymerization where the active polymer chain end is a free radical.

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Living polymerization

In polymer chemistry, living polymerization is a form of chain growth polymerization where the ability of a growing polymer chain to terminate has been removed.

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Lubricant

A lubricant is a substance, usually organic, introduced to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move.

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Macromolecule

A macromolecule is a very large molecule, such as protein, commonly created by the polymerization of smaller subunits (monomers).

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Maurice Morton

Maurice Morton (3 June 1913 – 23 March 1994) was a polymer author, educator, and researcher.

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Melting point

The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid at atmospheric pressure.

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Micelle

A micelle or micella (plural micelles or micellae, respectively) is an aggregate (or supramolecular assembly) of surfactant molecules dispersed in a liquid colloid.

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Molecular mass

Relative Molecular mass or molecular weight is the mass of a molecule.

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Molecule

A molecule is an electrically neutral group of two or more atoms held together by chemical bonds.

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Nanoelectronics

Nanoelectronics refer to the use of nanotechnology in electronic components.

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Paul Flory

Paul John Flory (June 19, 1910 – September 9, 1985) was an American chemist and Nobel laureate who was known for his work in the field of polymers, or macromolecules.

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PH

In chemistry, pH is a logarithmic scale used to specify the acidity or basicity of an aqueous solution.

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Photoresist

A photoresist is a light-sensitive material used in several processes, such as photolithography and photoengraving, to form a patterned coating on a surface.

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Polyamide

A polyamide is a macromolecule with repeating units linked by amide bonds.

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Polymer

A polymer (Greek poly-, "many" + -mer, "part") is a large molecule, or macromolecule, composed of many repeated subunits.

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Radius of gyration

Radius of gyration or gyradius of a body about an axis of rotation is defined as the radial distance of a point from the axis of rotation at which, if whole mass of the body is assumed to be concentrated, its moment of inertia about the given axis would be the same as with its actual distribution of mass.

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Rheology

Rheology (from Greek ῥέω rhéō, "flow" and -λoγία, -logia, "study of") is the study of the flow of matter, primarily in a liquid state, but also as "soft solids" or solids under conditions in which they respond with plastic flow rather than deforming elastically in response to an applied force.

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Ring-opening metathesis polymerisation

Ring-opening metathesis polymerization (ROMP) is a type of olefin metathesis chain-growth polymerization that produces industrially important products.

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Ring-opening polymerization

In polymer chemistry, ring-opening polymerization (ROP) is a form of chain-growth polymerization, in which the terminal end of a polymer chain acts as a reactive center where further cyclic monomers can react by opening its ring system and form a longer polymer chain (see figure).

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Self-assembly

Self-assembly is a process in which a disordered system of pre-existing components forms an organized structure or pattern as a consequence of specific, local interactions among the components themselves, without external direction.

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Size-exclusion chromatography

Size-exclusion chromatography (SEC), also known as molecular sieve chromatography, is a chromatographic method in which molecules in solution are separated by their size, and in some cases molecular weight.

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Sol–gel process

In materials science, the sol–gel process is a method for producing solid materials from small molecules.

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Solubility

Solubility is the property of a solid, liquid or gaseous chemical substance called solute to dissolve in a solid, liquid or gaseous solvent.

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Solvent

A solvent (from the Latin solvō, "loosen, untie, solve") is a substance that dissolves a solute (a chemically distinct liquid, solid or gas), resulting in a solution.

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Static light scattering

Static light scattering is a technique in physical chemistry that measures the intensity of the scattered light to obtain the average molecular weight Mw of a macromolecule like a polymer or a protein in solution.

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Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions.

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Supramolecular chemistry

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Telechelic polymer

A telechelic polymer or oligomer is a prepolymer capable of entering into further polymerization or other reactions through its reactive end-groups.

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Temperature

Temperature is a physical quantity expressing hot and cold.

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Thermoplastic elastomer

Thermoplastic elastomers (TPE), sometimes referred to as thermoplastic rubbers, are a class of copolymers or a physical mix of polymers (usually a plastic and a rubber) which consist of materials with both thermoplastic and elastomeric properties.

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Viscosity

The viscosity of a fluid is the measure of its resistance to gradual deformation by shear stress or tensile stress.

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Viscosity index

The viscosity index (VI) is an arbitrary, unitless measure of the change of viscosity with temperature, mostly used to characterize the viscosity-temperature behavior of lubricating oils.

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References

[1] https://en.wikipedia.org/wiki/Star-shaped_polymer

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