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2,3-Wittig rearrangement

Index 2,3-Wittig rearrangement

The -Wittig rearrangement is the transformation of an allylic ether into a homoallylic alcohol via a concerted, pericyclic process. [1]

9 relations: Georg Wittig, List of organic reactions, Organolithium reagent, Outline of organic chemistry, Sigmatropic reaction, W. Clark Still, Wittig, 1,2-Wittig rearrangement, 2,3-sigmatropic rearrangement.

Georg Wittig

Georg Wittig (June 16, 1897 – August 26, 1987) was a German chemist who reported a method for synthesis of alkenes from aldehydes and ketones using compounds called phosphonium ylides in the Wittig reaction.

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List of organic reactions

Well-known reactions and reagents in organic chemistry include.

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Organolithium reagent

Organolithium reagents are organometallic compounds that contain carbon – lithium bonds.

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Outline of organic chemistry

The following outline is provided as an overview of and topical guide to organic chemistry: Organic chemistry – scientific study of the structure, properties, composition, reactions, and preparation (by synthesis or by other means) of carbon-based compounds, hydrocarbons, and their derivatives.

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Sigmatropic reaction

A sigmatropic reaction in organic chemistry is a pericyclic reaction wherein the net result is one σ-bond is changed to another σ-bond in an uncatalyzed intramolecular process.

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W. Clark Still

W.

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Wittig

Wittig is a surname, and may refer to.

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1,2-Wittig rearrangement

A 1,2-Wittig rearrangement is a categorization of chemical reactions in organic chemistry, and consists of a 1,2-rearrangement of an ether with an alkyllithium compound.

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2,3-sigmatropic rearrangement

2,3-Sigmatropic rearrangements are a type of sigmatropic rearrangements and can be classified into two types.

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References

[1] https://en.wikipedia.org/wiki/2,3-Wittig_rearrangement

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