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Two-dimensional nuclear magnetic resonance spectroscopy

Index Two-dimensional nuclear magnetic resonance spectroscopy

Two-dimensional nuclear magnetic resonance spectroscopy (2D NMR) is a set of nuclear magnetic resonance spectroscopy (NMR) methods which give data plotted in a space defined by two frequency axes rather than one. [1]

28 relations: Butanone, Contour line, Fourier transform, Free induction decay, HNCA experiment, HNCOCA experiment, Insensitive nuclei enhanced by polarization transfer, Isotope, J-coupling, Jean Jeener, Magnetization transfer, Molecular mass, Molecule, Natural abundance, Nuclear magnetic resonance spectroscopy, Nuclear magnetic resonance spectroscopy of proteins, Nuclear Overhauser effect, Pulsed field gradient, Radio frequency, Richard R. Ernst, Rotational correlation time, Sequential walking, Spectral density, Spin echo, Spin–lattice relaxation, Triple-resonance nuclear magnetic resonance spectroscopy, Two-dimensional correlation analysis, Unified atomic mass unit.

Butanone

Butanone, also known as methyl ethyl ketone (MEK), is an organic compound with the formula CH3C(O)CH2CH3.

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Contour line

A contour line (also isocline, isopleth, isarithm, or equipotential curve) of a function of two variables is a curve along which the function has a constant value, so that the curve joins points of equal value.

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Fourier transform

The Fourier transform (FT) decomposes a function of time (a signal) into the frequencies that make it up, in a way similar to how a musical chord can be expressed as the frequencies (or pitches) of its constituent notes.

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Free induction decay

In Fourier transform nuclear magnetic resonance spectroscopy, free induction decay (FID) is the observable NMR signal generated by non-equilibrium nuclear spin magnetization precessing about the magnetic field (conventionally along z).

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HNCA experiment

HNCA is a 3D triple-resonance NMR experiment commonly used in the field of protein NMR.

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HNCOCA experiment

HNCOCA is a 3D triple-resonance NMR experiment commonly used in the field of protein NMR.

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Insensitive nuclei enhanced by polarization transfer

Insensitive nuclei enhanced by polarization transfer (INEPT) is a signal resolution enhancement method used in NMR spectroscopy.

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Isotope

Isotopes are variants of a particular chemical element which differ in neutron number.

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J-coupling

In nuclear chemistry and nuclear physics, Scalar or J-couplings (also called indirect dipole–dipole coupling) are mediated through chemical bonds connecting two spins.

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Jean Jeener

Jean Louis Charles Jeener is a Belgian physical chemist and physicist, well known for his experimental and theoretical contributions to spin thermodynamics in solids and for his invention of Two-dimensional nuclear magnetic resonance spectroscopy.

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Magnetization transfer

Magnetization transfer (MT), in NMR and MRI, refers to the transfer of nuclear spin polarization and/or spin coherence from one population of nuclei to another population of nuclei, and to techniques that make use of these phenomena.

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Molecular mass

Relative Molecular mass or molecular weight is the mass of a molecule.

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Molecule

A molecule is an electrically neutral group of two or more atoms held together by chemical bonds.

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Natural abundance

In physics, natural abundance (NA) refers to the abundance of isotopes of a chemical element as naturally found on a planet.

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Nuclear magnetic resonance spectroscopy

Nuclear magnetic resonance spectroscopy, most commonly known as NMR spectroscopy or magnetic resonance spectroscopy (MRS), is a spectroscopic technique to observe local magnetic fields around atomic nuclei.

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Nuclear magnetic resonance spectroscopy of proteins

Nuclear magnetic resonance spectroscopy of proteins (usually abbreviated protein NMR) is a field of structural biology in which NMR spectroscopy is used to obtain information about the structure and dynamics of proteins, and also nucleic acids, and their complexes.

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Nuclear Overhauser effect

The nuclear Overhauser effect (NOE or nOe) is the transfer of nuclear spin polarization from one spin bath to another spin bath via cross-relaxation.

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Pulsed field gradient

A pulsed field gradient is a short, timed pulse with spatial-dependent field intensity.

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Radio frequency

Radio frequency (RF) refers to oscillatory change in voltage or current in a circuit, waveguide or transmission line in the range extending from around twenty thousand times per second to around three hundred billion times per second, roughly between the upper limit of audio and the lower limit of infrared.

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Richard R. Ernst

Richard Robert Ernst (born 14 August 1933) is a Swiss physical chemist and Nobel Laureate.

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Rotational correlation time

Rotational correlation time (\tau_c) is the average time it takes for a molecule to rotate one radian.

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Sequential walking

Sequential walking is a technique that can be used to solve various 2D NMR spectra.

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Spectral density

The power spectrum S_(f) of a time series x(t) describes the distribution of power into frequency components composing that signal.

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Spin echo

In magnetic resonance, a spin echo is the refocusing of spin magnetisation by a pulse of resonant electromagnetic radiation.

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Spin–lattice relaxation

Spin–lattice relaxation is the mechanism by which the component of the magnetization vector along the direction of the static magnetic field reaches thermodynamic equilibrium with its surroundings (the "lattice") in nuclear magnetic resonance and magnetic resonance imaging.

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Triple-resonance nuclear magnetic resonance spectroscopy

Triple resonance experiments are a set of multi-dimensional nuclear magnetic resonance spectroscopy (NMR) experiments that link three types of atomic nuclei, most typically consisting of 1H, 15N and 13C.

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Two-dimensional correlation analysis

Two dimensional correlation analysis is a mathematical technique that is used to study changes in measured signals.

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Unified atomic mass unit

The unified atomic mass unit or dalton (symbol: u, or Da) is a standard unit of mass that quantifies mass on an atomic or molecular scale (atomic mass).

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Redirects here:

2D NMR, 2D-NMR, 2DNMR, 2d nmr, COSY, Correlation spectroscopy, Cosy spectrum, HMBC, HMQC, HOHAHA, INADEQUATE, J-resolved spectroscopy, NOESY, Noesy, TOCSY, Two-dimensional NMR.

References

[1] https://en.wikipedia.org/wiki/Two-dimensional_nuclear_magnetic_resonance_spectroscopy

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