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Nitroaldol reaction

Index Nitroaldol reaction

The Henry Reaction (also referred to as the nitro-aldol reaction) is a classic carbon–carbon bond formation reaction in organic chemistry. [1]

39 relations: Aldehyde, Aldol reaction, Amprenavir, Angewandte Chemie, Arabidopsis thaliana, Arkivoc, Bulletin de la Société Chimique de France, C2-Symmetric ligands, Cannizzaro reaction, Catalysis, Chemistry: A European Journal, Comptes rendus de l'Académie des Sciences, Diastereomer, Dipole, Enantiomer, Enantioselective synthesis, Ephedrine, Hevea brasiliensis, Journal of Biotechnology, Journal of the American Chemical Society, Ketone, N,N-Diisopropylethylamine, Nitro compound, Nitroalkene, Nitromethane, Organic and Biomolecular Chemistry, Organic chemistry, Organocatalysis, Propranolol, Quinine, Shibasaki catalysts, Stereoselectivity, Steric effects, Synthesis (journal), Tetrahedron (journal), Tetrahedron Letters, Triflate, Zinc, (S)-hydroxynitrile lyase.

Aldehyde

An aldehyde or alkanal is an organic compound containing a functional group with the structure −CHO, consisting of a carbonyl center (a carbon double-bonded to oxygen) with the carbon atom also bonded to hydrogen and to an R group, which is any generic alkyl or side chain.

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Aldol reaction

The aldol reaction is a means of forming carbon–carbon bonds in organic chemistry.

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Amprenavir

Amprenavir (original brand name Agenerase, GlaxoSmithKline) is a protease inhibitor used to treat HIV infection.

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Angewandte Chemie

Angewandte Chemie (meaning "Applied Chemistry") is a weekly peer-reviewed scientific journal that is published by Wiley-VCH on behalf of the German Chemical Society (Gesellschaft Deutscher Chemiker).

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Arabidopsis thaliana

Arabidopsis thaliana, the thale cress, mouse-ear cress or arabidopsis, is a small flowering plant native to Eurasia and Africa.

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Arkivoc

Arkivoc (Archive for Organic Chemistry) is a peer-reviewed open access scientific journal covering all aspects of organic chemistry.

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Bulletin de la Société Chimique de France

The Bulletin de la Société Chimique de France was a French peer-reviewed scientific journal on chemistry published by the Société Chimique de France.

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C2-Symmetric ligands

In homogeneous catalysis, a C2-symmetric ligands usually describes bidentate ligands that are dyssymmetric but not asymmetric by virtue of their C2-symmetry.

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Cannizzaro reaction

The Cannizzaro reaction, named after its discoverer Stanislao Cannizzaro, is a chemical reaction that involves the base-induced disproportionation of a non-enolizable aldehyde.

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Catalysis

Catalysis is the increase in the rate of a chemical reaction due to the participation of an additional substance called a catalysthttp://goldbook.iupac.org/C00876.html, which is not consumed in the catalyzed reaction and can continue to act repeatedly.

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Chemistry: A European Journal

Chemistry: A European Journal is a peer-reviewed scientific journal that publishes articles on all areas of chemistry and related fields.

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Comptes rendus de l'Académie des Sciences

Comptes rendus de l'Académie des Sciences (English: Proceedings of the Academy of sciences), or simply Comptes rendus, is a French scientific journal which has been published since 1666.

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Diastereomer

Diastereomers (sometimes called diastereoisomers) are a type of a stereoisomer.

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Dipole

In electromagnetism, there are two kinds of dipoles.

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Enantiomer

In chemistry, an enantiomer, also known as an optical isomer (and archaically termed antipode or optical antipode), is one of two stereoisomers that are mirror images of each other that are non-superposable (not identical), much as one's left and right hands are the same except for being reversed along one axis (the hands cannot be made to appear identical simply by reorientation).

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Enantioselective synthesis

Enantioselective synthesis, also called asymmetric synthesis, is a form of chemical synthesis.

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Ephedrine

Ephedrine is a medication and stimulant.

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Hevea brasiliensis

Hevea brasiliensis, the Pará rubber tree, sharinga tree, seringueira, or, most commonly, the rubber tree or rubber plant, is a tree belonging to the family Euphorbiaceae.

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Journal of Biotechnology

Journal of Biotechnology is a peer-reviewed scientific journal covering research ranging from genetic and molecular biological positions to biochemical, chemical, or bioprocess engineering aspects as well as research on the computer application of new software concepts which are directly relevant to biotechnology.

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Journal of the American Chemical Society

The Journal of the American Chemical Society (also known as JACS) is a weekly peer-reviewed scientific journal that was established in 1879 by the American Chemical Society.

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Ketone

In chemistry, a ketone (alkanone) is an organic compound with the structure RC(.

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N,N-Diisopropylethylamine

N,N-Diisopropylethylamine, or Hünig's base, DIPEA or DIEA, is an organic compound and an amine.

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Nitro compound

Nitro compounds are organic compounds that contain one or more nitro functional groups (−2).

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Nitroalkene

A nitroalkene, or nitro olefin, is a functional group combining the functionality of its constituent parts, an alkene and nitro group, while displaying its own chemical properties through alkene activation, making the functional group useful in specialty reactions such as the Michael reaction or Diels-Alder additions.

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Nitromethane

Nitromethane is an organic compound with the chemical formula.

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Organic and Biomolecular Chemistry

Organic & Biomolecular Chemistry is a biweekly peer-reviewed scientific journal covering all aspects of organic chemistry, including organic aspects of chemical biology, medicinal chemistry, natural product chemistry, supramolecular chemistry, macromolecular chemistry, theoretical chemistry, and catalysis.

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Organic chemistry

Organic chemistry is a chemistry subdiscipline involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms.

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Organocatalysis

In organic chemistry, the term organocatalysis (a portmanteau of the terms "organic" and "catalyst") refers to a form of catalysis, whereby the rate of a chemical reaction is increased by an organic catalyst referred to as an "organocatalyst" consisting of carbon, hydrogen, sulfur and other nonmetal elements found in organic compounds.

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Propranolol

Propranolol, sold under the brand name Inderal among others, is a medication of the beta blocker type. It is used to treat high blood pressure, a number of types of irregular heart rate, thyrotoxicosis, capillary hemangiomas, performance anxiety, and essential tremors. It is used to prevent migraine headaches, and to prevent further heart problems in those with angina or previous heart attacks. It can be taken by mouth or by injection into a vein. The formulation that is taken by mouth comes in short-acting and long-acting versions. Propranolol appears in the blood after 30 minutes and has a maximum effect between 60 and 90 minutes when taken by mouth. Common side effects include nausea, abdominal pain, and constipation. It should not be used in those with an already slow heart rate and most of those with heart failure. Quickly stopping the medication in those with coronary artery disease may worsen symptoms. It may worsen the symptoms of asthma. Caution is recommended in those with liver or kidney problems. Propranolol may cause harmful effects in the baby if taken during pregnancy. Its use during breastfeeding is probably safe, but the baby should be monitored for side effects. It is a non-selective beta blocker which works by blocking β-adrenergic receptors. Propranolol was discovered in 1964. It is on the World Health Organization's List of Essential Medicines, the most effective and safe medicines needed in a health system. Propranolol is available as a generic medication. The wholesale cost in the developing world is between 0.24 and 2.16 per month as of 2014. In the United States it costs about $15 per month at a typical dose.

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Quinine

Quinine is a medication used to treat malaria and babesiosis.

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Shibasaki catalysts

Shibasaki catalysts are a class of hetero-bimetallic complexes with the general formula (M.

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Stereoselectivity

In chemistry, stereoselectivity is the property of a chemical reaction in which a single reactant forms an unequal mixture of stereoisomers during the non-stereospecific creation of a new stereocenter or during the non-stereospecific transformation of a pre-existing one.

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Steric effects

Steric effects are nonbonding interactions that influence the shape (conformation) and reactivity of ions and molecules.

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Synthesis (journal)

Synthesis is a scientific journal published from 1969 to the present day by Thieme.

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Tetrahedron (journal)

Tetrahedron is a weekly peer-reviewed scientific journal covering the field of organic chemistry.

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Tetrahedron Letters

Tetrahedron Letters is a weekly international journal for rapid publication of full original research papers in the field of organic chemistry.

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Triflate

Triflate, also known by the systematic name trifluoromethanesulfonate, is a functional group with the formula CF3SO3−.

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Zinc

Zinc is a chemical element with symbol Zn and atomic number 30.

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(S)-hydroxynitrile lyase

(S)-hydroxynitrile lyase ((S)-cyanohydrin producing hydroxynitrile lyase, (S)-oxynitrilase, (S)-HbHNL, (S)-MeHNL, hydroxynitrile lyase, oxynitrilase, HbHNL, MeHNL, (S)-selective hydroxynitrile lyase, (S)-cyanohydrin carbonyl-lyase (cyanide forming), hydroxynitrilase) is an enzyme with systematic name (S)-cyanohydrin lyase (cyanide forming).

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Henry reaction, Kamlet reaction, Nitroaldol.

References

[1] https://en.wikipedia.org/wiki/Nitroaldol_reaction

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