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39 relations: Akira Suzuki (chemist), Alkene, Alkyne, Amine, Bis(triphenylphosphine)palladium chloride, Boronic acid, Buchwald–Hartwig amination, Column chromatography, Copper(I) iodide, Coupling reaction, Ei-ichi Negishi, Grignard reaction, Halocarbon, Heck reaction, Heck–Matsuda reaction, Hiyama coupling, Homogeneous catalysis, Ion-exchange resin, Kumada coupling, Lability, Negishi coupling, Nobel Prize in Chemistry, Organosilicon, Organotin chemistry, Organozinc compound, Palladium, Palladium(II) acetate, Persistent carbene, Phenol, Richard F. Heck, Silica gel, Sonogashira coupling, Stille reaction, Suzuki reaction, Tetrakis(triphenylphosphine)palladium(0), Thiol, Toxic heavy metal, Transmetalation, (1,1'-Bis(diphenylphosphino)ferrocene)palladium(II) dichloride.
Akira Suzuki (chemist)
is a Japanese chemist and Nobel Prize Laureate (2010), who first published the Suzuki reaction, the organic reaction of an aryl- or vinyl-boronic acid with an aryl- or vinyl-halide catalyzed by a palladium(0) complex, in 1979.
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Alkene
In organic chemistry, an alkene is an unsaturated hydrocarbon that contains at least one carbon–carbon double bond.
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Alkyne
In organic chemistry, an alkyne is an unsaturated hydrocarbon containing at least one carbon—carbon triple bond.
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Amine
In organic chemistry, amines are compounds and functional groups that contain a basic nitrogen atom with a lone pair.
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Bis(triphenylphosphine)palladium chloride
Bis(triphenylphosphine)palladium chloride is a coordination compound of palladium containing two triphenylphosphine and two chloride ligands.
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Boronic acid
A boronic acid is a compound related to boric acid in which one of the three hydroxyl groups is replaced by an alkyl or aryl group.
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Buchwald–Hartwig amination
The Buchwald–Hartwig amination is a chemical reaction used in organic chemistry for the synthesis of carbon–nitrogen bonds via the palladium-catalyzed cross-coupling of amines with aryl halides.
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Column chromatography
Column chromatography in chemistry is a chromatography method used to isolate a single chemical compound from a mixture.
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Copper(I) iodide
Copper(I) iodide is the inorganic compound with the formula CuI.
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Coupling reaction
A coupling reaction in organic chemistry is a general term for a variety of reactions where two hydrocarbon fragments are coupled with the aid of a metal catalyst.
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Ei-ichi Negishi
is a Manchurian-born Japanese chemist who has spent most of his career at Purdue University in the United States.
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Grignard reaction
The Grignard reaction (pronounced) is an organometallic chemical reaction in which alkyl, vinyl, or aryl-magnesium halides (Grignard reagents) add to a carbonyl group in an aldehyde or ketone.
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Halocarbon
Halocarbon compounds are chemicals in which one or more carbon atoms are linked by covalent bonds with one or more halogen atoms (fluorine, chlorine, bromine or iodine –) resulting in the formation of organofluorine compounds, organochlorine compounds, organobromine compounds, and organoiodine compounds.
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Heck reaction
The Heck reaction (also called the Mizoroki-Heck reaction) is the chemical reaction of an unsaturated halide (or triflate) with an alkene in the presence of a base and a palladium catalyst (or palladium nanomaterial-based catalyst) to form a substituted alkene.
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Heck–Matsuda reaction
The Heck-Matsuda (HM) reaction is an organic reaction and a type of palladium catalysed arylation of olefins that uses arenediazonium salts as an alternative to aryl halides and triflates.
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Hiyama coupling
The Hiyama coupling is a palladium-catalyzed cross-coupling reaction of organosilanes with organic halides used in organic chemistry to form carbon–carbon bonds (C-C bonds).
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Homogeneous catalysis
In chemistry, homogeneous catalysis is catalysis in a solution by a soluble catalyst.
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Ion-exchange resin
An ion-exchange resin or ion-exchange polymer is a resin or polymer that acts as a medium for ion exchange.
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Kumada coupling
In organic chemistry, the Kumada coupling is a type of cross coupling reaction, useful for generating carbon–carbon bonds by the reaction of a Grignard reagent and an organic halide.
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Lability
Lability refers to something that is constantly undergoing change or something that is likely to undergo change.
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Negishi coupling
The Negishi coupling is a widely employed transition metal catalyzed cross-coupling reaction.
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Nobel Prize in Chemistry
The Nobel Prize in Chemistry (Nobelpriset i kemi) is awarded annually by the Royal Swedish Academy of Sciences to scientists in the various fields of chemistry.
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Organosilicon
Organosilicon compounds are organometallic compounds containing carbon–silicon bonds.
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Organotin chemistry
Organotin compounds or stannanes are chemical compounds based on tin with hydrocarbon substituents.
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Organozinc compound
Organozinc compounds in organic chemistry contain carbon to zinc chemical bonds.
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Palladium
Palladium is a chemical element with symbol Pd and atomic number 46.
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Palladium(II) acetate
Palladium(II) acetate is a chemical compound of palladium described by the formula n, abbreviated n. It is more reactive than the analogous platinum compound.
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Persistent carbene
A persistent carbene (also known as stable carbene) is a type of carbene demonstrating particular stability.
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Phenol
Phenol, also known as phenolic acid, is an aromatic organic compound with the molecular formula C6H5OH.
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Richard F. Heck
Richard Frederick Heck (August 15, 1931 – October 10, 2015) was an American chemist noted for the discovery and development of the Heck reaction, which uses palladium to catalyze organic chemical reactions that couple aryl halides with alkenes.
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Silica gel
Silica gel is an amorphous and porous form of silicon dioxide (silica), consisting of an irregular tridimensional framework of alternating silicon and oxygen atoms with nanometer-scale voids and pores.
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Sonogashira coupling
The Sonogashira reaction is a cross-coupling reaction used in organic synthesis to form carbon–carbon bonds.
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Stille reaction
The Stille reaction, or the Migita–Kosugi–Stille coupling, is a chemical reaction widely used in organic synthesis which involves the coupling of an organotin compound (also known as organostannanes) with a variety of organic electrophiles via palladium-catalyzed coupling reaction.
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Suzuki reaction
The Suzuki reaction is an organic reaction, classified as a coupling reaction, where the coupling partners are a boronic acid and an organohalide catalyzed by a palladium(0) complex.
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Tetrakis(triphenylphosphine)palladium(0)
Tetrakis(triphenylphosphine)palladium(0) (sometimes called quatrotriphenylphosphine) is the chemical compound Pd4, often abbreviated Pd(PPh3)4, or rarely PdP4.
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Thiol
Thiol is an organosulfur compound that contains a carbon-bonded sulfhydryl (R–SH) group (where R represents an alkyl or other organic substituent).
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Toxic heavy metal
A toxic heavy metal is any relatively dense metal or metalloid that is noted for its potential toxicity, especially in environmental contexts.
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Transmetalation
Transmetalation (alt. spelling: transmetallation) is a type of organometallic reaction that involves the transfer of ligands from one metal to another.
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(1,1'-Bis(diphenylphosphino)ferrocene)palladium(II) dichloride
palladium(II) dichloride is a palladium complex containing the bidentate ligand 1,1'-bis(diphenylphosphino)ferrocene (dppf), abbreviated as.
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Palladium coupling reaction, Palladium coupling reactions, Palladium-catalysed cross coupling, Palladium-catalyzed, Palladium-catalyzed coupling reaction, Palladium-catalyzed cross-coupling, Palladium-catalyzed reactions, Palladium-coupling reactions.
References
[1] https://en.wikipedia.org/wiki/Palladium-catalyzed_coupling_reactions
