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Perkow reaction

Index Perkow reaction

The Perkow reaction is an organic reaction in which a trialkyl phosphite ester reacts with a haloketone to form a dialkyl vinyl phosphate and an alkyl halide. [1]

33 relations: Adenosine monophosphate, Adenosine triphosphate, Alkene, Alkoxide, Base (chemistry), Beilstein Journal of Organic Chemistry, Butyl group, Chemische Berichte, Cycloaddition, Enol, Enol ether, Furan, Haloalkane, Haloketone, Hexachloroacetone, Horner–Wadsworth–Emmons reaction, Journal of the American Chemical Society, Leaving group, Letters in Organic Chemistry, Michaelis–Arbuzov reaction, Molecules (journal), Nucleophilic addition, Organic reaction, Phenyl group, Phosphate, Phosphite ester, Phosphorylation, Quinoline, Reaction mechanism, Reagent, Substituent, Triethylphosphite, Vinyl group.

Adenosine monophosphate

Adenosine monophosphate (AMP), also known as 5'-adenylic acid, is a nucleotide.

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Adenosine triphosphate

Adenosine triphosphate (ATP) is a complex organic chemical that participates in many processes.

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Alkene

In organic chemistry, an alkene is an unsaturated hydrocarbon that contains at least one carbon–carbon double bond.

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Alkoxide

An alkoxide is the conjugate base of an alcohol and therefore consists of an organic group bonded to a negatively charged oxygen atom.

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Base (chemistry)

In chemistry, bases are substances that, in aqueous solution, release hydroxide (OH−) ions, are slippery to the touch, can taste bitter if an alkali, change the color of indicators (e.g., turn red litmus paper blue), react with acids to form salts, promote certain chemical reactions (base catalysis), accept protons from any proton donor, and/or contain completely or partially displaceable OH− ions.

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Beilstein Journal of Organic Chemistry

The Beilstein Journal of Organic Chemistry is a peer-reviewed open-access scientific journal established in 2005.

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Butyl group

In organic chemistry, butyl is a four-carbon alkyl radical or substituent group with general chemical formula −C4H9, derived from either of the two isomers of butane.

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Chemische Berichte

Chemische Berichte (usually abbreviated as Ber. or Chem. Ber.) was a German-language scientific journal of all disciplines of chemistry founded in 1868.

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Cycloaddition

A cycloaddition is a pericyclic chemical reaction, in which "two or more unsaturated molecules (or parts of the same molecule) combine with the formation of a cyclic adduct in which there is a net reduction of the bond multiplicity." The resulting reaction is a cyclization reaction.

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Enol

Enols, or more formally, alkenols, are a type of reactive structure or intermediate in organic chemistry that is represented as an alkene (olefin) with a hydroxyl group attached to one end of the alkene double bond.

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Enol ether

An enol ether is an alkene with an alkoxy substituent.

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Furan

Furan is a heterocyclic organic compound, consisting of a five-membered aromatic ring with four carbon atoms and one oxygen.

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Haloalkane

The haloalkanes (also known as halogenoalkanes or alkyl halides) are a group of chemical compounds derived from alkanes containing one or more halogens.

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Haloketone

A haloketone in organic chemistry is a functional group consisting of a ketone group or more generally a carbonyl group with an α-halogen substituent.

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Hexachloroacetone

Hexachloroacetone is an organic compound with the formula (Cl3C)2CO.

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Horner–Wadsworth–Emmons reaction

The Horner–Wadsworth–Emmons (HWE) reaction is a chemical reaction used in organic chemistry of stabilized phosphonate carbanions with aldehydes (or ketones) to produce predominantly E-alkenes.

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Journal of the American Chemical Society

The Journal of the American Chemical Society (also known as JACS) is a weekly peer-reviewed scientific journal that was established in 1879 by the American Chemical Society.

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Leaving group

In chemistry, a leaving group is a molecular fragment that departs with a pair of electrons in heterolytic bond cleavage.

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Letters in Organic Chemistry

Letters in Organic Chemistry (usually abbreviated as Lett. Org. Chem.), is a peer-reviewed monthly scientific journal, published since 2004 by Bentham Science Publishers.

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Michaelis–Arbuzov reaction

The Michaelis–Arbuzov reaction (also called the Arbuzov reaction) is the chemical reaction of a trialkyl phosphite and an alkyl halide to form a phosphonate.

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Molecules (journal)

Molecules is a peer-reviewed open access scientific journal that focuses on all aspects of synthetic organic chemistry and natural product chemistry.

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Nucleophilic addition

In organic chemistry, a nucleophilic addition reaction is an addition reaction where a chemical compound with an electron-deficient or electrophilic double or triple bond, a π bond, reacts with electron-rich reactant, termed a nucleophile, with disappearance of the double bond and creation of two new single, or σ, bonds.

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Organic reaction

Organic reactions are chemical reactions involving organic compounds.

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Phenyl group

In organic chemistry, the phenyl group or phenyl ring is a cyclic group of atoms with the formula C6H5.

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Phosphate

A phosphate is chemical derivative of phosphoric acid.

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Phosphite ester

In chemistry a phosphite ester or organophosphite usually refers to an organophosphorous compound with the formula P(OR)3.

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Phosphorylation

In chemistry, phosphorylation of a molecule is the attachment of a phosphoryl group.

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Quinoline

Quinoline is a heterocyclic aromatic organic compound with the chemical formula C9H7N.

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Reaction mechanism

In chemistry, a reaction mechanism is the step by step sequence of elementary reactions by which overall chemical change occurs.

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Reagent

A reagent is a substance or compound added to a system to cause a chemical reaction, or added to test if a reaction occurs.

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Substituent

In organic chemistry and biochemistry, a substituent is an atom or group of atoms which replaces one or more hydrogen atoms on the parent chain of a hydrocarbon, becoming a moiety of the resultant new molecule.

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Triethylphosphite

Triethylphosphite is an organophosphorus compound with the formula P(OCH2CH3)3, often abbreviated P(OEt)3.

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Vinyl group

In chemistry, vinyl or ethenyl is the functional group with the formula −CH.

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References

[1] https://en.wikipedia.org/wiki/Perkow_reaction

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