Potassium bis(trimethylsilyl)amide

Potassium bis(trimethylsilyl)amide (commonly abbreviated as KHMDS, Potassium(K) HexaMethylDiSilazide) is the chemical compound with the formula ((CH3)3Si)2NK. ^[1]

7 relations: Inorganic Chemistry (journal), Ion association, Lithium bis(trimethylsilyl)amide, Lithium diisopropylamide, Metal bis(trimethylsilyl)amides, Sigma-Aldrich, Sodium bis(trimethylsilyl)amide.

Inorganic Chemistry (journal)

Inorganic Chemistry is a biweekly peer-reviewed scientific journal published by the American Chemical Society since 1962.

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Ion association

In chemistry, ion association is a chemical reaction whereby ions of opposite electrical charge come together in solution to form a distinct chemical entity.

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Lithium bis(trimethylsilyl)amide

Lithium bis(trimethylsilyl)amide is a lithiated organosilicon compound with the formula LiN(SiMe3)2.

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Lithium diisopropylamide

Lithium diisopropylamide (commonly abbreviated LDA) is a chemical compound with the molecular formula 2NLi.

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Metal bis(trimethylsilyl)amides

Metal bis(trimethylsilyl)amides (often abbreviated as metal silylamides) are coordination complexes composed of a cationic metal with anionic bis(trimethylsilyl)amide ligands and are part of a broader category of metal amides.

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Sigma-Aldrich

Sigma-Aldrich Corporation is an American chemical, life science and biotechnology company owned by Merck KGaA.

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Sodium bis(trimethylsilyl)amide

Sodium bis(trimethylsilyl)amide is the organosilicon compound with the formula ((CH3)3Si)2NNa. This species, usually called NaHMDS (sodium hexamethyldisilazide), is a strong base used for deprotonation reactions or base-catalyzed reactions. Its advantages are that it is commercially available as a solid and it is soluble not only in ethers, such as THF or diethyl ether, but also in aromatic solvents, like benzene and toluene by virtue of the lipophilic TMS groups. NaHMDS is quickly destroyed by water to form sodium hydroxide and bis(trimethylsilyl)amine.

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Redirects here:

KHMDS, Potassium hexamethyldisilazane, Potassium hexamethyldisilazide.

References

[1] https://en.wikipedia.org/wiki/Potassium_bis(trimethylsilyl)amide

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