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27 relations: Antarafacial and suprafacial, Arthur C. Cope, Aza-Cope rearrangement, Bullvalene, Cis–trans isomerism, Claisen rearrangement, Cyclobutane, Cyclohexane conformation, David A. Evans, Diastereomer, Divinylcyclopropane-cycloheptadiene rearrangement, Double bond, Fluxional molecule, Hydroxy group, Journal of the American Chemical Society, Keto–enol tautomerism, Orbital overlap, Organic reaction, Radical (chemistry), Ring strain, Sigmatropic reaction, Stuart Schreiber, Symmetry, Transition state, Woodward–Hoffmann rules, 1,5-Cyclooctadiene, 1,5-Hexadiene.
Antarafacial and suprafacial
Antarafacial (Woodward-Hoffmann symbol a) and suprafacial (s) are two topological concepts in organic chemistry describing the relationship between two simultaneous chemical bond making and/or bond breaking processes in or around a reaction center.
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Arthur C. Cope
Arthur C. Cope (June 27, 1909 – June 4, 1966) was a highly successful and influential organic chemist and member of the National Academy of Sciences.
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Aza-Cope rearrangement
Rearrangements, especially those that can participate in cascade reactions, such as the aza-Cope rearrangements, are of high practical as well as conceptual importance in organic chemistry, due to their ability to quickly build structural complexity out of simple starting materials.
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Bullvalene
Bullvalene is a hydrocarbon with the chemical formula C10H10 with the unusual property that the chemical bonds making up the molecule are constantly rearranging as in fluxional molecules.
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Cis–trans isomerism
Cis–trans isomerism, also known as geometric isomerism or configurational isomerism, is a term used in organic chemistry.
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Claisen rearrangement
The Claisen rearrangement (not to be confused with the Claisen condensation) is a powerful carbon–carbon bond-forming chemical reaction discovered by Rainer Ludwig Claisen.
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Cyclobutane
Cyclobutane is a cycloalkane and organic compound with the formula (CH2)4.
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Cyclohexane conformation
A cyclohexane conformation is any of several three-dimensional shapes that a cyclohexane molecule can assume while maintaining the integrity of its chemical bonds.
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David A. Evans
David A. Evans (born 1941) is the Abbott and James Lawrence Professor Emeritus in the Department of Chemistry and Chemical Biology at Harvard University.
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Diastereomer
Diastereomers (sometimes called diastereoisomers) are a type of a stereoisomer.
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Divinylcyclopropane-cycloheptadiene rearrangement
The divinylcyclopropane-cycloheptadiene rearrangement is an organic chemical transformation that involves the isomerization of a 1,2-divinylcyclopropane into a cycloheptadiene or -triene.
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Double bond
A double bond in chemistry is a chemical bond between two chemical elements involving four bonding electrons instead of the usual two.
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Fluxional molecule
Fluxional molecules are molecules that undergo dynamics such that some or all of their atoms interchange between symmetry-equivalent positions.
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Hydroxy group
A hydroxy or hydroxyl group is the entity with the formula OH.
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Journal of the American Chemical Society
The Journal of the American Chemical Society (also known as JACS) is a weekly peer-reviewed scientific journal that was established in 1879 by the American Chemical Society.
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Keto–enol tautomerism
In organic chemistry, keto–enol tautomerism refers to a chemical equilibrium between a keto form (a ketone or an aldehyde) and an enol (an alcohol).
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Orbital overlap
In chemical bonds, an orbital overlap is the concentration of orbitals on adjacent atoms in the same regions of space.
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Organic reaction
Organic reactions are chemical reactions involving organic compounds.
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Radical (chemistry)
In chemistry, a radical (more precisely, a free radical) is an atom, molecule, or ion that has an unpaired valence electron.
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Ring strain
In organic chemistry, ring strain is a type of instability that exists when bonds in a molecule form angles that are abnormal.
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Sigmatropic reaction
A sigmatropic reaction in organic chemistry is a pericyclic reaction wherein the net result is one σ-bond is changed to another σ-bond in an uncatalyzed intramolecular process.
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Stuart Schreiber
Stuart L. Schreiber (born 6 February 1956) is a scientist at Harvard University and co-Founder of the Broad Institute.
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Symmetry
Symmetry (from Greek συμμετρία symmetria "agreement in dimensions, due proportion, arrangement") in everyday language refers to a sense of harmonious and beautiful proportion and balance.
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Transition state
The transition state of a chemical reaction is a particular configuration along the reaction coordinate.
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Woodward–Hoffmann rules
The Woodward–Hoffmann rules (or the pericyclic selection rules), devised by Robert Burns Woodward and Roald Hoffmann, are a set of rules used to rationalize or predict certain aspects of the stereochemical outcome and activation energy of pericyclic reactions, an important class of reactions in organic chemistry.
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1,5-Cyclooctadiene
1,5-Cyclooctadiene is the organic compound with the chemical formula C8H12.
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1,5-Hexadiene
1,5-Hexadiene is the organic compound with the formula (CH2)2(CH.
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References
[1] https://en.wikipedia.org/wiki/Cope_rearrangement
