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Oppenauer oxidation

Index Oppenauer oxidation

Oppenauer oxidation, named after Rupert Viktor Oppenauer, is a gentle method for selectively oxidizing secondary alcohols to ketones. [1]

20 relations: Alcohol oxidation, Aldehyde, Aluminium isopropoxide, Cannizzaro reaction, Cholesterol total synthesis, Dehydrogenation, Dess–Martin periodinane, Hydromorphone, List of inorganic reactions, List of organic reactions, Marker degradation, Meerwein–Ponndorf–Verley reduction, Melengestrol, Norethisterone, Outline of organic chemistry, Strain (chemistry), Tishchenko reaction, Transfer hydrogenation, Trifluoroacetone, 11-Deoxycorticosterone.

Alcohol oxidation

Alcohol oxidation is an important organic reaction.

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Aldehyde

An aldehyde or alkanal is an organic compound containing a functional group with the structure −CHO, consisting of a carbonyl center (a carbon double-bonded to oxygen) with the carbon atom also bonded to hydrogen and to an R group, which is any generic alkyl or side chain.

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Aluminium isopropoxide

Aluminium isopropoxide is the chemical compound usually described with the formula Al(O-i-Pr)3, where i-Pr is the isopropyl group (–CH(CH3)2).

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Cannizzaro reaction

The Cannizzaro reaction, named after its discoverer Stanislao Cannizzaro, is a chemical reaction that involves the base-induced disproportionation of a non-enolizable aldehyde.

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Cholesterol total synthesis

Cholesterol total synthesis in chemistry describes the total synthesis of the complex biomolecule cholesterol and is considered a great scientific achievement.

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Dehydrogenation

Dehydrogenation is a chemical reaction that involves the removal of hydrogen from an organic molecule.

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Dess–Martin periodinane

Dess–Martin periodinane (DMP) is a chemical reagent used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones.

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Hydromorphone

Hydromorphone, also known as dihydromorphinone, and sold under the brand name Dilaudid, among others, is a centrally acting pain medication of the opioid class.

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List of inorganic reactions

Well-known types of reactions that involve organic compounds include.

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List of organic reactions

Well-known reactions and reagents in organic chemistry include.

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Marker degradation

The Marker degradation is a three-step synthetic route in steroid chemistry developed by American chemist Russell Earl Marker in 1938–40.

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Meerwein–Ponndorf–Verley reduction

The Meerwein–Ponndorf–Verley (MPV) reduction in organic chemistry is the reduction of ketones and aldehydes to their corresponding alcohols utilizing aluminium alkoxide catalysis in the presence of a sacrificial alcohol.

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Melengestrol

Melengestrol (INN, BAN) is a steroidal progestin of the 17α-hydroxyprogesterone group and an antineoplastic drug which was never marketed.

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Norethisterone

Norethisterone, also known as norethindrone and sold under the brand names Aygestin and Primolut N among many others, is a progestin medication which is used in birth control pills, menopausal hormone therapy, and for the treatment of gynecological disorders.

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Outline of organic chemistry

The following outline is provided as an overview of and topical guide to organic chemistry: Organic chemistry – scientific study of the structure, properties, composition, reactions, and preparation (by synthesis or by other means) of carbon-based compounds, hydrocarbons, and their derivatives.

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Strain (chemistry)

In chemistry, a molecule experiences strain when its chemical structure undergoes some stress which raises its internal energy in comparison to a strain-free reference compound.

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Tishchenko reaction

The Tishchenko reaction is an organic chemical reaction that involves disproportionation of an aldehyde in the presence of an alkoxide.

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Transfer hydrogenation

Transfer hydrogenation is the addition of hydrogen (H2; dihydrogen in inorganic and organometallic chemistry) to a molecule from a source other than gaseous H2.

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Trifluoroacetone

Trifluoroacetone (1,1,1-trifluoroacetone) is an organofluorine compound with the chemical formula CF3C(O)CH3.

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11-Deoxycorticosterone

11-Deoxycorticosterone (DOC), or simply deoxycorticosterone, also known as 21-hydroxyprogesterone, as well as desoxycortone (INN), deoxycortone, and cortexone, is a steroid hormone produced by the adrenal gland that possesses mineralocorticoid activity and acts as a precursor to aldosterone.

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Redirects here:

Oppenauer Oxidation, Oppenauer-Woodward oxidation, Oppenauer–Woodward oxidation.

References

[1] https://en.wikipedia.org/wiki/Oppenauer_oxidation

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