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35 relations: Air-free technique, Alcohol, Ammonia, Chemical formula, Condensation reaction, Deprotonation, Derivative (chemistry), Electron microscope, Ether, Gas chromatography, Heterocyclic compound, Hexamethyldisiloxane, Hydrolysis, Inorganic Syntheses, Lithium bis(trimethylsilyl)amide, Mass spectrometry, Metal bis(trimethylsilyl)amides, Microwave chemistry, N-Butyllithium, Non-nucleophilic base, Organic synthesis, Organometallic chemistry, Organosilicon, Photolithography, Photoresist, Potassium bis(trimethylsilyl)amide, Pyrolysis, Rain-X, Reagent, Royal Society of Chemistry, Sodium bis(trimethylsilyl)amide, Supercritical drying, Trimethylsilyl, Trimethylsilyl chloride, Xanthine.
Air-free technique
Air-free techniques refer to a range of manipulations in the chemistry laboratory for the handling of compounds that are air-sensitive.
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Alcohol
In chemistry, an alcohol is any organic compound in which the hydroxyl functional group (–OH) is bound to a carbon.
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Ammonia
Ammonia is a compound of nitrogen and hydrogen with the formula NH3.
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Chemical formula
A chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, commas and plus (+) and minus (−) signs.
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Condensation reaction
A condensation reaction is a class of an organic addition reaction that proceeds in a step-wise fashion to produce the addition product, usually in equilibrium, and a water molecule (hence named condensation).
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Deprotonation
Deprotonation is the removal (transfer) of a proton (a hydrogen cation, H+) from a Brønsted–Lowry acid in an acid-base reaction.
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Derivative (chemistry)
In chemistry, a derivative is a compound that is derived from a similar compound by a chemical reaction.
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Electron microscope
An electron microscope is a microscope that uses a beam of accelerated electrons as a source of illumination.
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Ether
Ethers are a class of organic compounds that contain an ether group—an oxygen atom connected to two alkyl or aryl groups.
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Gas chromatography
Gas chromatography (GC) is a common type of chromatography used in analytical chemistry for separating and analyzing compounds that can be vaporized without decomposition.
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Heterocyclic compound
A heterocyclic compound or ring structure is a cyclic compound that has atoms of at least two different elements as members of its ring(s).
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Hexamethyldisiloxane
Hexamethyldisiloxane (HMDSO) is an organosilicon compound with the formula O2.
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Hydrolysis
Hydrolysis is a term used for both an electro-chemical process and a biological one.
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Inorganic Syntheses
Inorganic Syntheses is a book series which aims to publish "detailed and foolproof" procedures for the synthesis of inorganic compounds.
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Lithium bis(trimethylsilyl)amide
Lithium bis(trimethylsilyl)amide is a lithiated organosilicon compound with the formula LiN(SiMe3)2.
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Mass spectrometry
Mass spectrometry (MS) is an analytical technique that ionizes chemical species and sorts the ions based on their mass-to-charge ratio.
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Metal bis(trimethylsilyl)amides
Metal bis(trimethylsilyl)amides (often abbreviated as metal silylamides) are coordination complexes composed of a cationic metal with anionic bis(trimethylsilyl)amide ligands and are part of a broader category of metal amides.
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Microwave chemistry
Microwave chemistry is the science of applying microwave radiation to chemical reactions.
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N-Butyllithium
n-Butyllithium (abbreviated n-BuLi) is an organolithium reagent.
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Non-nucleophilic base
As the name suggests, a non-nucleophilic base is a sterically hindered organic base that is a poor nucleophile.
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Organic synthesis
Organic synthesis is a special branch of chemical synthesis and is concerned with the intentional construction of organic compounds.
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Organometallic chemistry
Organometallic chemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal, including alkaline, alkaline earth, and transition metals, and sometimes broadened to include metalloids like boron, silicon, and tin, as well.
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Organosilicon
Organosilicon compounds are organometallic compounds containing carbon–silicon bonds.
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Photolithography
Photolithography, also termed optical lithography or UV lithography, is a process used in microfabrication to pattern parts of a thin film or the bulk of a substrate.
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Photoresist
A photoresist is a light-sensitive material used in several processes, such as photolithography and photoengraving, to form a patterned coating on a surface.
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Potassium bis(trimethylsilyl)amide
Potassium bis(trimethylsilyl)amide (commonly abbreviated as KHMDS, Potassium(K) HexaMethylDiSilazide) is the chemical compound with the formula ((CH3)3Si)2NK.
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Pyrolysis
Pyrolysis is the thermal decomposition of materials at elevated temperatures in an inert atmosphere.
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Rain-X
Rain-X is a synthetic hydrophobic surface-applied product that causes water to bead, most commonly used on glass automobile surfaces.
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Reagent
A reagent is a substance or compound added to a system to cause a chemical reaction, or added to test if a reaction occurs.
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Royal Society of Chemistry
The Royal Society of Chemistry (RSC) is a learned society (professional association) in the United Kingdom with the goal of "advancing the chemical sciences".
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Sodium bis(trimethylsilyl)amide
Sodium bis(trimethylsilyl)amide is the organosilicon compound with the formula ((CH3)3Si)2NNa. This species, usually called NaHMDS (sodium hexamethyldisilazide), is a strong base used for deprotonation reactions or base-catalyzed reactions. Its advantages are that it is commercially available as a solid and it is soluble not only in ethers, such as THF or diethyl ether, but also in aromatic solvents, like benzene and toluene by virtue of the lipophilic TMS groups. NaHMDS is quickly destroyed by water to form sodium hydroxide and bis(trimethylsilyl)amine.
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Supercritical drying
Supercritical drying is a process to remove liquid in a precise and controlled way.
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Trimethylsilyl
A trimethylsilyl group (abbreviated TMS) is a functional group in organic chemistry.
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Trimethylsilyl chloride
Trimethylsilyl chloride, also known as chlorotrimethylsilane is an organosilicon compound (silyl halide), with the formula (CH3)3SiCl, often abbreviated Me3SiCl or TMSCl.
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Xanthine
Xanthine (or; archaically xanthic acid) (3,7-dihydropurine-2,6-dione), is a purine base found in most human body tissues and fluids and in other organisms.
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Bis(trimethylsilyl)amide, C6H19NSi2, Hexamethyldisilazane, Hexamethyldisilazide, Hexamethyldisilazides.
References
[1] https://en.wikipedia.org/wiki/Bis(trimethylsilyl)amine
