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Organocerium chemistry

Index Organocerium chemistry

Organocerium compounds are chemical compounds that contain one or more chemical bond between carbon and cerium. [1]

44 relations: Acyl group, Addition reaction, Alcohol, Alkene, Alkyl, Alkyne, Amine, Antibiotic, Ate complex, Base (chemistry), Bridging ligand, Carbon, Catalysis, Cerium, Cerium(III) chloride, Chemical bond, Chemical compound, Conjugated system, Coordination complex, Dehydration reaction, Diethyl ether, Electrophile, Enol, Functional group, Gilman reagent, Grignard reaction, Hydrate, Imine, Lanthanide, Lewis acids and bases, Luche reduction, Nucleophile, Organic synthesis, Organolanthanide chemistry, Organolithium reagent, Oxidation state, Oxophilicity, Pentamethylcyclopentadiene, Polymer, Roseophilin, Tetrahydrofuran, Total synthesis, Transmetalation, Treatment of cancer.

Acyl group

An acyl group is a moiety derived by the removal of one or more hydroxyl groups from an oxoacid, including inorganic acids.

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Addition reaction

An addition reaction, in organic chemistry, is in its simplest terms an organic reaction where two or more molecules combine to form the larger one (the adduct).

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Alcohol

In chemistry, an alcohol is any organic compound in which the hydroxyl functional group (–OH) is bound to a carbon.

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Alkene

In organic chemistry, an alkene is an unsaturated hydrocarbon that contains at least one carbon–carbon double bond.

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Alkyl

In organic chemistry, an alkyl substituent is an alkane missing one hydrogen.

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Alkyne

In organic chemistry, an alkyne is an unsaturated hydrocarbon containing at least one carbon—carbon triple bond.

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Amine

In organic chemistry, amines are compounds and functional groups that contain a basic nitrogen atom with a lone pair.

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Antibiotic

An antibiotic (from ancient Greek αντιβιοτικά, antibiotiká), also called an antibacterial, is a type of antimicrobial drug used in the treatment and prevention of bacterial infections.

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Ate complex

An ate complex in chemistry is a salt formed by the reaction of a Lewis acid with a Lewis base whereby the central atom (from the Lewis acid) increases its valence and gains a negative formal charge.

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Base (chemistry)

In chemistry, bases are substances that, in aqueous solution, release hydroxide (OH−) ions, are slippery to the touch, can taste bitter if an alkali, change the color of indicators (e.g., turn red litmus paper blue), react with acids to form salts, promote certain chemical reactions (base catalysis), accept protons from any proton donor, and/or contain completely or partially displaceable OH− ions.

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Bridging ligand

In coordination chemistry, a bridging ligand is a ligand that connects two or more atoms, usually metal ions.

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Carbon

Carbon (from carbo "coal") is a chemical element with symbol C and atomic number 6.

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Catalysis

Catalysis is the increase in the rate of a chemical reaction due to the participation of an additional substance called a catalysthttp://goldbook.iupac.org/C00876.html, which is not consumed in the catalyzed reaction and can continue to act repeatedly.

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Cerium

Cerium is a chemical element with symbol Ce and atomic number 58.

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Cerium(III) chloride

Cerium(III) chloride (CeCl3), also known as cerous chloride or cerium trichloride, is a compound of cerium and chlorine.

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Chemical bond

A chemical bond is a lasting attraction between atoms, ions or molecules that enables the formation of chemical compounds.

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Chemical compound

A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) composed of atoms from more than one element held together by chemical bonds.

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Conjugated system

In chemistry, a conjugated system is a system of connected p-orbitals with delocalized electrons in molecules which are conventionally represented as having alternating single and multiple bonds, which in general may lower the overall energy of the molecule and increase stability.

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Coordination complex

In chemistry, a coordination complex consists of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands or complexing agents.

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Dehydration reaction

In chemistry and the biological sciences, a dehydration reaction, also known as Zimmer's hydrogenesis, is a chemical reaction that involves the loss of a water molecule from the reacting molecule.

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Diethyl ether

Diethyl ether, or simply ether, is an organic compound in the ether class with the formula, sometimes abbreviated as (see Pseudoelement symbols).

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Electrophile

In organic chemistry, an electrophile is a reagent attracted to electrons.

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Enol

Enols, or more formally, alkenols, are a type of reactive structure or intermediate in organic chemistry that is represented as an alkene (olefin) with a hydroxyl group attached to one end of the alkene double bond.

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Functional group

In organic chemistry, functional groups are specific substituents or moieties within molecules that are responsible for the characteristic chemical reactions of those molecules.

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Gilman reagent

A Gilman reagent is a lithium and copper (diorganocopper) reagent compound, R2CuLi, where R is an alkyl or aryl.

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Grignard reaction

The Grignard reaction (pronounced) is an organometallic chemical reaction in which alkyl, vinyl, or aryl-magnesium halides (Grignard reagents) add to a carbonyl group in an aldehyde or ketone.

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Hydrate

In chemistry, a hydrate is a substance that contains water or its constituent elements.

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Imine

An imine is a functional group or chemical compound containing a carbon–nitrogen double bond.

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Lanthanide

The lanthanide or lanthanoid series of chemical elements comprises the 15 metallic chemical elements with atomic numbers 57 through 71, from lanthanum through lutetium.

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Lewis acids and bases

A Lewis acid is a chemical species that contains an empty orbital which is capable of accepting an electron pair from a Lewis base to form a Lewis adduct.

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Luche reduction

Luche reduction is the selective organic reduction of α,β-unsaturated ketones to allylic alcohols with sodium borohydride (NaBH4) and lanthanide chlorides, mainly cerium(III) chloride (CeCl3), in methanol or ethanol.

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Nucleophile

Nucleophile is a chemical species that donates an electron pair to an electrophile to form a chemical bond in relation to a reaction.

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Organic synthesis

Organic synthesis is a special branch of chemical synthesis and is concerned with the intentional construction of organic compounds.

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Organolanthanide chemistry

Organolanthanide chemistry is the field of chemistry that studies compounds with a lanthanide-to-carbon bond.

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Organolithium reagent

Organolithium reagents are organometallic compounds that contain carbon – lithium bonds.

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Oxidation state

The oxidation state, sometimes referred to as oxidation number, describes degree of oxidation (loss of electrons) of an atom in a chemical compound.

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Oxophilicity

Oxophilicity is the tendency of certain chemical compounds to form oxides by hydrolysis or abstraction of oxygen, often from organic compounds.

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Pentamethylcyclopentadiene

1,2,3,4,5-Pentamethylcyclopentadiene is a cyclic dialkene with the formula C5Me5H (Me.

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Polymer

A polymer (Greek poly-, "many" + -mer, "part") is a large molecule, or macromolecule, composed of many repeated subunits.

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Roseophilin

Roseophilin is an antibiotic isolated from Streptomyces griscovirides shown to have antitumor activity.

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Tetrahydrofuran

Tetrahydrofuran (THF) is an organic compound with the formula (CH2)4O.

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Total synthesis

Total synthesis is the complete chemical synthesis of a complex molecule, often a natural product, from simple, commercially available precursors.

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Transmetalation

Transmetalation (alt. spelling: transmetallation) is a type of organometallic reaction that involves the transfer of ligands from one metal to another.

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Treatment of cancer

Cancer can be treated by surgery, chemotherapy, radiation therapy, hormonal therapy, targeted therapy (including immunotherapy such as monoclonal antibody therapy) and synthetic lethality.

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Organocerium, Organocerium compound.

References

[1] https://en.wikipedia.org/wiki/Organocerium_chemistry

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